Optical temperature sensitivity, up-conversion luminescence and structure of Ca5 (PO4)3F: Yb3+, Ho3+, Tm3+ glass-ceramics

被引:9
作者
Gao, Zhixin [1 ]
Xing, Junhao [1 ]
Luo, Ying [2 ]
Liu, Mengyuan [1 ]
Yang, Linrong [1 ]
Shang, Fei [1 ]
Chen, Guohua [1 ]
机构
[1] Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R China
[2] China Nonferrous Met Guilin Geol & Min Co Ltd, Guangxi Key Lab Superhard Mat, Natl Engn Res Ctr Special Mineral Mat, Guilin 541004, Peoples R China
基金
中国国家自然科学基金;
关键词
Glass ceramics; Energy transfer; Up-conversion luminescence; Optical temperature measurement; ENERGY-TRANSFER; HYDROTHERMAL SYNTHESIS; DOWN-CONVERSION; CA-5(PO4)(3)F; EMISSION; THERMOMETRY; IONS; ER3+;
D O I
10.1016/j.optcom.2022.128951
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The melt quenching and subsequent controlled crystallization method was used to prepare Yb3+/Ho3+/Tm3+ triple-doped Ca-5(PO4)(3)F glass ceramics (GCs), and the structural, optical property, luminescence and temperature sensitivity characteristics were characterized by structural and spectral analysis. The results show that Ca-5(PO4)(3)F nanoparticles are precipitated in the precursor glass (PG). GC820 sample exhibits Sr-max = 1.91% K-1 and Sa-max = 0.475 parts per thousand K-1 based on thermally coupled emitting state. Meanwhile, according to the nonthermally coupled emitting state, the GC820 specimen displays Sr-max = 1.23% K-1 and Sa-max = 5.94% K-1. This finding indicates that Ca-5(PO4)(3)F: Yb3+, Ho3+, and Tm3+ GCs are promising materials for optical thermometry.
引用
收藏
页数:13
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