Investigation of the dielectric and optic properties of rosehip seed extract loaded hydrogels

被引:9
作者
Okutan, M. [1 ]
Coskun, R. [2 ]
Yalcin, O. [3 ]
Babucoglu, A. C. [4 ]
Demir, A. [5 ]
机构
[1] Univ Siegen, Inst High Frequency & Quantum Elect, D-57068 Siegen, Germany
[2] Yozgat Bozok Univ, Dept Chem, TR-66500 Yozgat, Turkiye
[3] Nigde Omer Halisdemir Univ, Dept Phys, TR-51240 Nigde, Turkiye
[4] Nigde Omer Halisdemir Univ, Inst Sci, TR-51240 Nigde, Turkiye
[5] Duzce Univ, Dept Phys, TR-81620 Duzce, Turkiye
关键词
Hydrogels; Rosehip seed (RS) extract; Dielectric properties; Organic conductivity; Electrochemical biosensor; Smith chart; DOPED GRAPHENE HYDROGELS; SYNTHETIC CIRCUITS; BROWNIAN-MOTION; POLYMER; MODULUS; SUPERCAPACITOR; CONDUCTIVITY; PERFORMANCE; ORIGIN;
D O I
10.1016/j.molstruc.2022.134480
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Rosehip seed (RS) extract-loaded hydrogel samples RS1 (poly(AMPS-co-MBAAm), RS2 (poly(AMPS-co - CrA-co -MBAAm)), RS3 (poly(AMPS -co -MAA -co -MBAAm)) and RS4 (poly(AMPS-co -IA - co-MBAAm)) were prepared to examine their structural and optical properties. Furthermore, frequency and bias voltage evolution of dielectric and electrical parameters were analyzed using impedance spec-troscopy (IS) for all samples at room temperature (RT). Fluctuating and self-consistent results were ob-tained in the Ultraviolet-visible (UV) spectrum of the samples. The conductivity mechanisms were de-termined by calculating the s parameters of all samples for different regions. The complex impedance, capacitance, phase angles, dielectric constant, tangent factor, electric modulus, and frequency variation of ionic conductivity for the rosehip seed loaded hydrogel were successfully analyzed in detail using IS in the broadband frequency range. The increase in ionic conductivity of the RS-doped hydrogel with in-creasing frequency was attributed to its ability to exhibit the Langevin equivalent of Brownian motion in viscoelastic fluids, surface/bulk Maxwellian stress relaxation behavior, and the validity of the Stokes -Einstein relationship in biological fluids. In particular, the capacitive effect observed as a result of the Cole-Cole diagrams of the dielectric constant adapting to Smith Chat and the equivalent RC circuit al-lowed the material to be used as a capacitor. (c) 2022 Elsevier B.V. All rights reserved.
引用
收藏
页数:8
相关论文
共 37 条
[1]   Hydrogel: Preparation, characterization, and applications: A review [J].
Ahmed, Enas M. .
JOURNAL OF ADVANCED RESEARCH, 2015, 6 (02) :105-121
[2]  
[Anonymous], 1907, Zeitschrift fur Chemie und Industrie der Kolloide, V1, P213, DOI DOI 10.1007/BF01830147
[3]   State of water and ionic conductivity of solid polymer electrolyte membranes in relation to polymer actuators [J].
Asaka, K ;
Fujiwara, N ;
Oguro, K ;
Onishi, K ;
Sewa, S .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 505 (1-2) :24-32
[4]   Recent advances in hydrogels in terms of fast stimuli responsiveness and superior mechanical performance [J].
Bin Imran, Abu ;
Seki, Takahiro ;
Takeoka, Yukikazu .
POLYMER JOURNAL, 2010, 42 (11) :839-851
[5]   Using hydroxylamine as a reducer to prepare N-doped graphene hydrogels used in high-performance energy storage [J].
Chang, Yunzhen ;
Han, Gaoyi ;
Yuan, Jinping ;
Fu, Dongying ;
Liu, Feifei ;
Li, Sidian .
JOURNAL OF POWER SOURCES, 2013, 238 :492-500
[6]   Hydrothermal synthesis of macroscopic nitrogen-doped graphene hydrogels for ultrafast supercapacitor [J].
Chen, Ping ;
Yang, Jing-Jing ;
Li, Shan-Shan ;
Wang, Zheng ;
Xiao, Tian-Yuan ;
Qian, Yu-Hong ;
Yu, Shu-Hong .
NANO ENERGY, 2013, 2 (02) :249-256
[7]   Origin of the synthetic circuits and comparison effects of different dose malachite green oxalate doped hydrogel [J].
Coskun, R. ;
Okutan, M. ;
Ozturk, M. ;
Yalcin, O. .
MATERIALS CHEMISTRY AND PHYSICS, 2019, 222 :361-368
[8]   Impedance properties and comparison effects of different dose safranin doped hydrogels [J].
Coskun, R. ;
Yalcin, O. ;
Okutan, M. ;
Ozturk, M. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2017, 460 :153-160
[9]  
Coskun R, 2012, ACTA PHYS POL A, V122, P683
[10]   Highly Stretchable, Strain Sensing Hydrogel Optical Fibers [J].
Guo, Jingjing ;
Liu, Xinyue ;
Jiang, Nan ;
Yetisen, Ali K. ;
Yuk, Hyunwoo ;
Yang, Changxi ;
Khademhosseini, Ali ;
Zhao, Xuanhe ;
Yun, Seok-Hyun .
ADVANCED MATERIALS, 2016, 28 (46) :10244-10249