Sulfur-Enriched Nanoporous Carbon: A Novel Approach to CO2 Adsorption

被引:59
作者
Liu, Chen [1 ]
Zhi, Yue [1 ]
Yu, Qiyun [1 ]
Tian, Lifeng [1 ]
Demir, Muslum [7 ,8 ]
Colak, Suleyman Gokhan [2 ]
Farghaly, Ahmed A. [3 ,4 ,6 ]
Wang, Linlin [5 ]
Hu, Xin [1 ]
机构
[1] Zhejiang Normal Univ, Key Lab, Minist Educ Adv Catalysis Mat, Jinhua 321004, Zhejiang, Peoples R China
[2] Iskenderun Tech Univ, Fac Engn & Nat Sci, Dept Biomed Engn, TR-31200 Hatay, Turkiye
[3] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA
[4] Univ Chicago, Pritzker Sch Mol Engn, Chicago, IL 60637 USA
[5] Zhejiang Normal Univ, Coll Engn, Key Lab Urban Rail Transit Intelligent Operat & M, Jinhua 321004, Zhejiang, Peoples R China
[6] Assiut Univ, Fac Sci, Chem Dept, Assiut 71516, Egypt
[7] Bogazici Univ, Dept Chem Engn, TR-34342 Istanbul, Turkiye
[8] TUBITAK Marmara Res Ctr, Mat Inst, TR-41470 Gebze, Turkiye
关键词
porous nanocarbons; S-doping; CO2; adsorption; biomass; potassium persulfate; ACTIVATED CARBON; POROUS CARBON; ORGANIC FRAMEWORKS; HIGH-PERFORMANCE; FACILE SYNTHESIS; DOPED CARBON; PORE-SIZE; DIOXIDE; CAPTURE; STORAGE;
D O I
10.1021/acsanm.3c06239
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Carbon dioxide (CO2) intake plays a vital role in sustaining the environmental balance by influencing global carbon dynamics and climatic stability. This work addresses the production of sulfur-doped porous nanocarbons (SDCs) as prospective sorbents for CO2 capture. SDCs were fabricated by utilizing coconut shell as a carbon precursor and potassium persulfate as both a chemical activating agent and a sulfur dopant. The incorporation of sulfur functionalities into carbon matrices creates structural variability and active sites, boosting CO2 absorption capabilities. Sulfur's peculiar electrical structure allows greater intermolecular interactions with CO2, enhancing adsorption affinities. According to the experimental data, the CO2 uptake was best measured as 3.37 mmol/g at 0(degrees)C and 1 bar and 2.56 mmol/g at 25 C-degrees and 1 bar. The results show that the higher porosity of SDC materials adds to a large amplification in the CO2 uptake capability. The work underlines the delicate interaction between sulfur doping, morphological porosity, and surface reactivity in enhancing the effectiveness of CO2 sequestration. SDC materials hold considerable promise in tackling the present ecological concerns and developing CO2 collection techniques. The suggested single-step synthesis technique described here provides a sustainable and environmentally friendly method for synthesizing SDCs for carbon capture applications.
引用
收藏
页码:5434 / 5441
页数:8
相关论文
共 61 条
[1]   CO2 capture from biogas by biomass-based adsorbents: A review [J].
Aghel, Babak ;
Behaein, Sara ;
Alobiad, Falah .
FUEL, 2022, 328
[2]   Incorporating Gadolinium Oxide (Gd2O3) as a Rare Earth Metal Oxide in Carbon Nanofiber Skeleton for Supercapacitor Application [J].
Aydin, Hamide ;
Ustun, Burcu ;
Kurtan, Umran ;
Aslan, Ayse ;
Karakus, Selcan .
CHEMELECTROCHEM, 2024, 11 (03)
[3]   Sulfonated poly (ether ether ketone) based carbon dioxide gas sensor: Impact of sulfonation degree on sensing behavior at different humid condition [J].
Bag, Souvik ;
Pal, Kaushik .
SENSORS AND ACTUATORS B-CHEMICAL, 2020, 303
[4]   Sulfur-Doped porous carbon Adsorbent: A promising solution for effective and selective CO2 capture [J].
Bai, Jiali ;
Shao, Jiawei ;
Yu, Qiyun ;
Demir, Muslum ;
Altay, Bilge Nazli ;
Ali, Turgunov Muhammad ;
Jiang, Yongfu ;
Wang, Linlin ;
Hu, Xin .
CHEMICAL ENGINEERING JOURNAL, 2024, 479
[5]   Synthesis and characterization of polyphenylene sulfide resin-derived S-doped porous carbons for efficient CO2 capture [J].
Bai, Jiali ;
Huang, Jiamei ;
Jiang, Qing ;
Jiang, Wenhao ;
Demir, Muslum ;
Kilic, Murat ;
Altay, Bilge Nazli ;
Wang, Linlin ;
Hu, Xin .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2023, 674
[6]   N-doped porous carbon derived from macadamia nut shell for CO2 adsorption [J].
Bai, Jiali ;
Huang, Jiamei ;
Yu, Qiyun ;
Demir, Muslum ;
Kilic, Murat ;
Altay, Bilge Nazli ;
Hu, Xin ;
Wang, Linlin .
FUEL PROCESSING TECHNOLOGY, 2023, 249
[7]   Fabrication of coconut shell-derived porous carbons for CO2 adsorption application [J].
Bai, Jiali ;
Huang, Jiamei ;
Yu, Qiyun ;
Demir, Muslum ;
Akgul, Eda ;
Altay, Bilge Nazli ;
Hu, Xin ;
Wang, Linlin .
FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING, 2023, 17 (08) :1122-1130
[8]   One-pot synthesis of self S-doped porous carbon for efficient CO2 adsorption [J].
Bai, Jiali ;
Huang, Jiamei ;
Yu, Qiyun ;
Demir, Muslum ;
Gecit, Fehime Hayal ;
Altay, Bilge Nazli ;
Wang, Linlin ;
Hu, Xin .
FUEL PROCESSING TECHNOLOGY, 2023, 244
[9]   Recent advances in functionalized micro and mesoporous carbon materials: synthesis and applications [J].
Benzigar, Mercy R. ;
Talapaneni, Siddulu Naidu ;
Joseph, Stalin ;
Ramadass, Kavitha ;
Singh, Gurwinder ;
Scaranto, Jessica ;
Ravon, Ugo ;
Al-Bahily, Khalid ;
Vinu, Ajayan .
CHEMICAL SOCIETY REVIEWS, 2018, 47 (08) :2680-2721
[10]   Synthesis of sulfur doped carbon from dipotassium anthraquinone-1,8-disulfonate for CO2 adsorption [J].
Cui, Hongmin ;
Xu, Jianguo ;
Shi, Jinsong ;
Zhang, Chao .
JOURNAL OF CO2 UTILIZATION, 2021, 50