Electrochemical Oxidative Dehydrogenative Coupling of Sulfoximines to Construct N-sulfenyl and N-phosphinyl Sulfoximines

被引：12

作者：

Li, Xiaoman ^{[1
]}

Huang, Jiawei ^{[1
]}

Xu, Liang ^{[1
]}

Liu, Jichang ^{[1
,2
]}

Wei, Yu ^{[1
]}

机构：

[1] Shihezi Univ, Sch Chem & Chem Engn, State Key Lab Incubat Base Green Proc Chem Engn, Shihezi 832003, Peoples R China

[2] East China Univ Sci & Technol, Sch Chem Engn, Shanghai 200237, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2023年 / 365卷 / 24期

基金：

中国国家自然科学基金;

关键词：

Electrochemistry; Dehydrocoupling; NH-sulfoximines; N-sulfenylation; N-phosphinylation; ALPHA-KETO ACIDS; ACCESS; DERIVATIVES; CHEMISTRY;

D O I：

10.1002/adsc.202300933

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Herein, an electrochemical oxidative approach for the synthesis of N-sulfenyl and N-phosphinyl sulfoximines has been established from readily available NH-sulfoximines with thiophenols and diarylphosphine oxides. Utilizing the synergistic effect of halide salt and electrochemical oxidation, the desired products are obtained at room temperature in the absence of any acidic/basic/metallic additives. image

引用

页码：4647 / 4653

页数：7

共 72 条

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