Hydrogen Bond-Directed Self-Assembly of a Novel Pyrene Derivative

被引:0
|
作者
Yu, Yang [1 ,2 ]
Zhao, Yuzhen [1 ]
Mi, Yongsheng [2 ]
Fang, Fengmei [3 ]
Zhang, Huimin [1 ]
Guo, Zhun [1 ]
Zhao, Yang [1 ]
Wang, Dong [2 ]
机构
[1] Xijing Univ, Sch Elect Informat, Xian Key Lab Adv Photoelect Mat & Energy Convers D, Xian 710123, Peoples R China
[2] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Dept Mat Phys & Chem, Beijing 100083, Peoples R China
[3] Yantai Xianhua Technol Grp Co Ltd, Yantai 264006, Peoples R China
关键词
pyrene derivatives; self-assembly; nano; micro structures; optoelectronic applications; PHYSICAL-PROPERTIES; BLOCK-COPOLYMERS; CLICK CHEMISTRY; SOLAR-CELLS;
D O I
10.3390/cryst13020342
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A symmetrical pyrene derivative chemical structure was prepared by a classical synthetic method such as the Sonogashira cross-coupling reaction. The molecular structure of the product was characterised in detail by nuclear magnetic resonance (NMR), mass spectrometry (MS) and other methods. Furthermore, the optical properties of the novel products were studied by UV-vis and photoluminescence spectroscopy. The electrochemical properties of the molecules were fully characterised by comparison of electrochemical experiments and DFT simulation. Scanning electron microscope (SEM) observed that the product successfully formed a regular self-assembly structure. The product verifies the role of the molecular structure of the disc-mounted molecules on the optical and self-assembly properties, and is of reference value in the field of organic optoelectronic molecules
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页数:10
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