Synthesis, crystal structure and Hirshfeld surface analysis of di-μ2-iodido-bis[(2,2'-biquinoline-κ2N,N')copper(I)]

被引：2

作者：

Temesgen, Ayalew W. ^{[1
]}

Novikov, Anton P. ^{[2
,3
]}

Tskhovrebov, Alexander G. ^{[2
]}

Kultyshkina, Ekaterina K. ^{[2
]}

Tuan Anh Le ^{[4
]}

机构：

[1] Univ Gondar, Coll Nat & Computat Sci, Dept Chem, Gondar 196, Ethiopia

[2] Peoples Friendship Univ Russia, RUDN Univ, 6 Miklukho Maklaya, Moscow 117198, Russia

[3] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, 31 Leninsky Prospekt Bldg 4, Moscow 119071, Russia

[4] Vietnam Natl Univ, Univ Sci, 334 Nguyen Trai, Hanoi 100000, Vietnam

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷

基金：

俄罗斯基础研究基金会;

关键词：

crystal structure; Hirshfeld surface; analysis; pi-pi stacking; biquinoline; copper; complex; COMPLEXES;

D O I：

10.1107/S2056989023000634

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The molecular and crystal structures of the title compound, [Cu2I2(C18H12N2)(2)], were examined by single-crystal X-ray diffraction and Hirshfeld surface analysis. The Cu atom is coordinated in a distorted tetrahedral geometry by two N atoms from the 2,2'-biquinoline ligands and the two mu(2)-bridging iodide ligands. The molecules are in contact via pi-pi-stacking interactions. Hirshfeld surface analysis showed that the most important contributions to the intermolecular interactions are H center dot center dot center dot H (39.7%), H center dot center dot center dot I/I center dot center dot center dot H (17.8%), C center dot center dot center dot H/H center dot center dot center dot C (17.5%), C center dot center dot center dot C (16.5%), N center dot center dot center dot C/C center dot center dot center dot N (3.9%) and N center dot center dot center dot H/H center dot center dot center dot N (3.5%).

引用

页码：132 / +

页数：9

共 16 条

[1]

[Anonymous], 2013, SAINT+

[2] Towards Anion Recognition and Precipitation with Water-Soluble 1,2,4-Selenodiazolium Salts: Combined Structural and Theoretical Study [J].

Artemjev, Alexey A. ;

Novikov, Anton P. ;

Burkin, Gleb M. ;

Sapronov, Alexander A. ;

Kubasov, Alexey S. ;

Nenajdenko, Valentine G. ;

Khrustalev, Victor N. ;

Borisov, Alexander V. ;

Kirichuk, Anatoly A. ;

Kritchenkov, Andreii S. ;

Gomila, Rosa M. ;

Frontera, Antonio ;

Tskhovrebov, Alexander G. .

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2022, 23 (12)

[3]

Bruker, 2018, APEX3

[4] Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands [J].

Delgado-Rebollo, Manuela ;

Garcia-Morales, Cristina ;

Maya, Celia ;

Prieto, Auxiliadora ;

Echavarren, Antonio M. ;

Perez, Pedro J. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2019, 898

[5] Preparation, reactivity and photoluminescence of copper(I) borohydride complexes with bis[(2-diphenylphosphino)phenyl] ether as chelating ligand [J].

Ferraro, Valentina ;

Castro, Jesus ;

Trave, Enrico ;

Bortoluzzi, Marco .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2022, 957

[6] Platinum anti-cancer drugs: Free radical mechanism of Pt-DNA adduct formation and anti-neoplastic effect [J].

Fong, Clifford W. .

FREE RADICAL BIOLOGY AND MEDICINE, 2016, 95 :216-229

[7] The Cambridge Structural Database [J].

Groom, Colin R. ;

Bruno, Ian J. ;

Lightfoot, Matthew P. ;

Ward, Suzanna C. .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2016, 72 :171-179

[8] Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination [J].

Krause, Lennard ;

Herbst-Irmer, Regine ;

Sheldrick, George M. ;

Stalke, Dietmar .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2015, 48 :3-10

[9] Synthesis and Characterization of New Guanine Complexes of Pt(IV) and Pd(II) by X-ray Diffraction and Hirshfeld Surface Analysis [J].

Novikov, Anton Petrovich ;

Volkov, Mikhail Alexandrovich ;

Safonov, Alexey Vladimirovich ;

Grigoriev, Mikhail Semenovich ;

Abkhalimov, Evgeny Vladilenovich .

CRYSTALS, 2021, 11 (11)

[10] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

← 1 2 →