Deficient MoS2 nanoflowers to promote polysulfide redox conversion in Lithium-Sulfur batteries

被引:1
作者
Niu, Aimin [1 ]
Liu, Huitao [2 ]
Tang, Xiaonan [1 ]
Zhuo, Shuping [1 ]
机构
[1] Shandong Univ Technol, Sch Chem & Chem Engn, Zibo 255000, Peoples R China
[2] Zibo Inst Prod Qual Inspect, Zibo 255063, Peoples R China
基金
中国国家自然科学基金;
关键词
defect-rich MoS2; Electro-catalysis; Shuttle effect; Lithium-sulfur batteries;
D O I
10.1016/j.matlet.2023.135232
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The shuttle effect and the slow conversion kinetics hinder the practical application of lithium-sulfur batteries. Herein, we synthesized the polypyrrole (PPy) coated defect-rich MoS2 nanoflowers (PPy@DR-MoS2) as sulfur host. Benefiting from the sulfur defects and PPy coating structure, the S/ppy-DR-MoS2 composite displays good cycling performance at a high current density of 1C and excellent cycling stability for over 300 cycles with a low cycling decline rate of 0.17% per cycle.
引用
收藏
页数:4
相关论文
共 16 条
[1]   Activating interfacial S sites of MoS2 boosts hydrogen evolution electrocatalysis [J].
Geng, Shuo ;
Tian, Fenyang ;
Li, Menggang ;
Liu, Yequn ;
Sheng, Jie ;
Yang, Weiwei ;
Yu, Yongsheng ;
Hou, Yanglong .
NANO RESEARCH, 2022, 15 (03) :1809-1816
[2]   MoS2-Coated N-doped Mesoporous Carbon Spherical Composite Cathode and CNT/Chitosan Modified Separator for Advanced Lithium Sulfur Batteries [J].
Jiang, Shouxin ;
Chen, Manfang ;
Wang, Xianyou ;
Wu, Zhenyu ;
Zeng, Peng ;
Huang, Cheng ;
Wang, Ying .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (12) :16828-+
[3]   Simultaneous Cobalt and Phosphorous Doping of MoS2 for Improved Catalytic Performance on Polysulfide Conversion in Lithium-Sulfur Batteries [J].
Lin, Haibin ;
Zhang, Shengliang ;
Zhang, Tianran ;
Ye, Hualin ;
Yao, Qiaofeng ;
Zheng, Guangyuan Wesley ;
Lee, Jim Yang .
ADVANCED ENERGY MATERIALS, 2019, 9 (38)
[4]   Propelling Polysulfide Conversion by Defect-Rich MoS2 Nanosheets for High-Performance Lithium-Sulfur Batteries [J].
Liu, Mengmeng ;
Zhang, Congcong ;
Su, Junming ;
Chen, Xiang ;
Ma, Tianye ;
Huang, Tao ;
Yu, Aishui .
ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (23) :20788-20795
[5]   Ultrathin nanosheets of FeOOH with oxygen vacancies as efficient polysulfide electrocatalyst for advanced lithium-sulfur batteries [J].
Lu, Jianhao ;
Wang, Zilong ;
Guo, Yang ;
Jin, Zhaoqing ;
Cao, Gaoping ;
Qiu, Jingyi ;
Lian, Fang ;
Wang, Anbang ;
Wang, Weikun .
ENERGY STORAGE MATERIALS, 2022, 47 :561-568
[6]   High Electrochemical Selectivity of Edge versus Terrace Sites in Two-Dimensional Layered MoS2 Materials [J].
Wang, Haotian ;
Zhang, Qianfan ;
Yao, Hongbin ;
Liang, Zheng ;
Lee, Hyun-Wook ;
Hsu, Po-Chun ;
Zheng, Guangyuan ;
Cui, Yi .
NANO LETTERS, 2014, 14 (12) :7138-7144
[7]   Three-dimensional MoS2/Carbon sandwiched architecture for boosted lithium storage capability [J].
Wu, Chenghao ;
Ou, Jian Zhen ;
He, Fengyi ;
Ding, Jianfeng ;
Luo, Wei ;
Wu, Minghong ;
Zhang, Haijiao .
NANO ENERGY, 2019, 65
[8]   Built-In Catalysis in Confined Nanoreactors for High-Loading Li-S Batteries [J].
Wu, Qingping ;
Yao, Zhenguo ;
Zhou, Xuejun ;
Xu, Jun ;
Cao, Fahai ;
Li, Chilin .
ACS NANO, 2020, 14 (03) :3365-3377
[9]   A simple, robust and fast method for embedding sulfur nanoparticles in Ti3C2Tx MXene as stable lithium-sulfur batteries cathodes [J].
Xue, Chaohui ;
Yue, Chun ;
Yuan, Le .
JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 886
[10]   Next-Generation Energy Storage Technologies and Their Key Electrode Materials [J].
Yang Ze ;
Zhang Wang ;
Shen Yue ;
Yuan Li-Xia ;
Huang Yun-Hui .
ACTA PHYSICO-CHIMICA SINICA, 2016, 32 (05) :1062-1071