Platinum Nanoclusters-Modified Porous In2O3 Nanocubes for Highly Sensitive and Selective Formaldehyde Gas Sensing at Room Temperature

被引:23
作者
Zhai, Liangyu [1 ]
Zhu, Gangqiang [1 ]
Rao, Fei [1 ]
Liu, Zehan [1 ]
Zhang, Weibin [2 ]
Zhu, Lujun [1 ]
Shi, Xianjin [3 ]
Huang, Yu [3 ]
Jia, Yanmin [1 ]
Hojamberdiev, Mirabbos [4 ]
机构
[1] Shaanxi Normal Univ, Sch Phys & Informat Technol, Xian 710062, Peoples R China
[2] Yunnan Normal Univ, Inst Phys & Elect Informat, Kunming 650500, Peoples R China
[3] Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol SKLLQG, Xian 710061, Peoples R China
[4] Tech Univ Berlin, Inst Chem, Str 17 Juni 135, D-10623 Berlin, Germany
基金
中国国家自然科学基金;
关键词
Indium oxide; Nanocubes; Platinum nanoclusters; Gas sensing; Formaldehyde; Selectivity; SENSOR; NANOSTRUCTURES; NANOPARTICLES; NANOFIBERS; NANOSHEETS; CO;
D O I
10.1016/j.snb.2023.134805
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The detection of formaldehyde gas generally requires a relatively high temperature. It is still challenging to simultaneously possess high sensitivity and strong selectivity for the detection of low-concentration formaldehyde at room temperature. The activation energy of the reaction can be reduced by introducing oxygen vacancies or loading the metal clusters on the surface of metal oxide-based semiconductors, leading to an improvement in the performance and detection limit of the sensor. However, this approach may lead to an increased cross sensitivity to other gases and a reduction in the selectivity of the sensors. In this study, In2O3 can capture a significant amount of adsorbed oxygen by increasing the oxygen vacancies and introducing platinum nano clusters on the surface of In2O3 synthesized with a specific morphology, leading to high sensitivity and selectivity for the detection of formaldehyde gas at room temperature. The Pt-In2O3 sensor exhibits a response value of approximately 38 to a concentration of 1 ppm formaldehyde gas at 20 degrees C. Moreover, the developed sensor demonstrates excellent performance in a complex atmosphere and exhibits good long-term stability. The achieved high sensitivity and selectivity for the detection of formaldehyde gas at low temperatures hold significant implications for research and practical applications in the field of sensors.
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页数:10
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