Synergistic growth of cobalt hydroxide on reduced graphene oxide/nickel foam for supercapacitor application

被引:42
作者
Jagtap, Chaitali [1 ]
Kadam, Vishal [1 ]
Kamble, Bhagyashri [2 ]
Lokhande, P. E. [1 ,5 ]
Pakdel, Amir [3 ]
Kumar, Deepak [4 ]
Udayabhaskar, R. [5 ]
Vedpathak, Amol [1 ]
Chaure, N. B. [1 ]
Pathan, H. M. [1 ]
机构
[1] Savitribai Phule Pune Univ, Dept Phys, Adv Phys Lab, Pune, India
[2] Shivaji Univ, Dept Chem, Kolhapur, India
[3] Univ Dublin, Trinity Coll Dublin, Dept Mech Mfg & Biomed Engn, Dublin, Ireland
[4] Lovely Profess Univ, Sch Chem Engn & Phys Sci, Dept Chem, Phagwara 144411, Punjab, India
[5] Univ Tecnol Metropolitana, Fac Ingn, Dept Mecan, Santiago, Chile
关键词
Cobalt hydroxide; Reduced graphene oxide; Supercapacitor; Energy density; Nanocomposite; ELECTRODE MATERIAL; NICKEL FOAM; PERFORMANCE; NANOSHEETS; OXIDE;
D O I
10.1016/j.est.2024.110666
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The electrode material plays a crucial role in achieving the superior performance of supercapacitors. The current study presents a quick and cost-effective method for synthesizing a binder-free Co(OH)2/rGO nanocomposite material decorated over Ni foam, showing promising potential for high-performance supercapacitor applications. The suggested electrode material was extensively characterized using various spectroscopy and electron microscopy techniques to investigate its structural and morphological properties. To assess the electrochemical performance of the Co(OH)2/rGO nanocomposite, cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) experiments were carried out in an appropriate electrolyte of 2 M KOH. Furthermore, electrochemical impedance spectroscopy (EIS) was employed to evaluate the interfacial charge transfer capability. The synthesized nanocomposite exhibited outstanding rate capability, with a maximum specific capacitance of 2688 Fg- 1 at a current density of 1Ag- 1. Further, a solid-state asymmetric Co(OH)2/rGO/AC supercapacitor coin-devise was fabricated which demonstrated notable energy density and power density of 28.34 Wkg- 1 and 1754 WhKg-1, respectively, along with excellent stability. These results highlight the potential of the hybrid material to be utilized as a flexible all-solid-state supercapacitor device in practical applications.
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页数:11
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