Ofloxacin and doxycycline competitive/binary adsorption on to MCM-41: isotherm modelling and evaluation

被引：1

作者：

Saxena, Mukul ^{[1
]}

Kushwaha, Jai Prakash ^{[2
]}

Kulshreshtha, Shweta ^{[1
]}

Kaur, Gurleenjot ^{[3
]}

Singh, Neetu ^{[2
]}

机构：

[1] Amity Univ Jaipur, Amity Inst Biotechnol, Jaipur, Rajasthan, India

[2] Thapar Inst Engn & Technol Deemed Univ, Dept Chem Engn, Patiala 147004, Punjab, India

[3] Thapar Inst Engn & Technol Deemed Univ, Sch Energy & Environm, Patiala, Punjab, India

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 2023年 / 61卷 / 01期

关键词：

Ofloxacin; doxycycline; binary adsorption; MCM-41; competitive; multicomponent adsorption; METAL-IONS; ACTIVATED CARBON; SURFACE; THERMODYNAMICS; ANTIBIOTICS; WATER;

D O I：

10.1080/00319104.2022.2098295

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This work investigates the competitive adsorption of ofloxacin (OXC) and doxycycline (DCL) form OXC-DCL binary solution on to MCM-41, not reported earlier. Experiments were conducted at 288-318 K temperatures, and equilibrium adsorption isotherm data were analysed to study the competitive effect of the presence and absence of DCL on OXC adsorption and vice-versa in OXC-DCL binary solution. On this basis, the competitive interaction, Synergistic, Antagonistic and No interaction effects, for OXC and DCL adsorption was evaluated. Furthermore, the experimental equilibrium adsorption data were used for isotherm modelling using various multi-component competitive isotherm models such as extended Langmuir, extended Freundlich and Sheindorf-Rebuhn-Sheintuch (SRS) isotherms. It was found that single component adsorption for OXC, and OXC adsorption in the presence of DCL and vice-versa followed Freundlich and extended Freundlich isotherm model, respectively. The competitive adsorption interaction between OXC and DCL from their binary solution was found to be antagonistic at all temperatures.

引用

页码：25 / 40

页数：16

共 39 条

[31] Insights into doxycycline adsorption onto graphene nanosheet: a combined quantum mechanics, thermodynamics, and kinetic study [J].

Rostamian, Rahele ;

Behnejad, Hassan .

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2018, 25 (03) :2528-2537

[32] A model for the structure of MCM-41 incorporating surface roughness [J].

Sonwane, CG ;

Jones, CW ;

Ludovice, PJ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (49) :23395-23404

[33] Multicomponent adsorption study of metal ions onto bagasse fly ash using Taguchi's design of experimental methodology [J].

Srivastava, Vimal C. ;

Mall, Indra D. ;

Mishra, Indra M. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (17) :5697-5706

[34] Adsorption thermodynamics and isosteric heat of adsorption of toxic metal ions onto bagasse fly ash (BFA) and rice husk ash (RHA) [J].

Srivastava, Virnal Chandra ;

Mall, Indra Deo ;

Mishra, Indra Mani .

CHEMICAL ENGINEERING JOURNAL, 2007, 132 (1-3) :267-278

[35] Aromatic amines equilibrium sorptive interaction with synthesized silica based mesoporous MCM-41: Physicochemical evaluation and isotherm modeling [J].

Toor, Sehaspreet Kaur ;

Kushwaha, Jai Prakash ;

Sangal, Vikas Kumar .

JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2019, 54 (04) :286-294

[36] Interaction of the fluoroquinolone antibiotic, ofloxacin, with titanium oxide nanoparticles in water: Adsorption and breakdown [J].

Van Wieren, Emily M. ;

Seymour, Michael D. ;

Peterson, Jonathan W. .

SCIENCE OF THE TOTAL ENVIRONMENT, 2012, 441 :1-9

[37] Single and binary adsorption of heavy metal ions from aqueous solutions using sugarcane cellulose-based adsorbent [J].

Wang, Futao ;

Pan, Yuanfeng ;

Cai, Pingxiong ;

Guo, Tianxiang ;

Xiao, Huining .

BIORESOURCE TECHNOLOGY, 2017, 241 :482-490

[38] Doxycycline treatment of high-risk COVID-19-positive patients with comorbid pulmonary disease [J].

Yates, Paul A. ;

Newman, Steven A. ;

Oshry, Lauren J. ;

Glassman, Robert H. ;

Leone, Ashton M. ;

Reichel, Elias .

THERAPEUTIC ADVANCES IN RESPIRATORY DISEASE, 2020, 14

[39] Ofloxacin Adsorption on Chitosan/Biochar Composite: Kinetics, Isotherms, and Effects of Solution Chemistry [J].

Zhu, Chunmiao ;

Lang, Yinhai ;

Liu, Ben ;

Zhao, Huaxuan .

POLYCYCLIC AROMATIC COMPOUNDS, 2019, 39 (03) :287-297

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