Tandem catalysis in electrocatalytic nitrate reduction: Unlocking efficiency and mechanism

被引：54
作者：
Wu, Ziyang [1 ]
Song, Yanhui [2 ]
Guo, Haocheng [3 ]
Xie, Fengting [1 ]
Cong, Yuting [1 ]
Kuang, Min [1 ,4 ]
Yang, Jianping [1 ,4 ]
机构：
[1] Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai, Peoples R China
[2] Taiyuan Univ Technol, Key Lab Interface Sci Engn Adv Mat, Minist Educ, Taiyuan 030024, Peoples R China
[3] Helmholtz Inst Ulm HIU, Ulm, Germany
[4] Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
来源：
INTERDISCIPLINARY MATERIALS | 2024年 / 3卷 / 02期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
efficiency; electrocatalytic nitrate reduction; mechanism; selectivity; tandem catalysts; NITROGEN; REMOVAL; OXYGEN; WATER;
D O I：
10.1002/idm2.12152
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electrochemical nitrate reduction reaction (NO3RR) holds promise for ecofriendly nitrate removal. However, the challenge of achieving high selectivity and efficiency in electrocatalyst systems still significantly hampers the mechanism understanding and the large-scale application. Tandem catalysts, comprising multiple catalytic components working synergistically, offer promising potential for improving the efficiency and selectivity of the NO3RR. This review highlights recent progress in designing tandem catalysts for electrochemical NO3RR, including the noble metal-related system, transition metal electrocatalysts, and pulsed electrocatalysis strategies. Specifically, the optimization of active sites, interface engineering, synergistic effects between catalyst components, various in situ technologies, and theory simulations are discussed in detail. Challenges and opportunities in the development of tandem catalysts for scaling up electrochemical NO3RR are further discussed, such as stability, durability, and reaction mechanisms. By outlining possible solutions for future tandem catalyst design, this review aims to open avenues for efficient nitrate reduction and comprehensive insights into the mechanisms for energy sustainability and environmental safety. This review summarizes the tandem catalysts design for high-performance electrocatalytic nitrate reduction reaction, utilizing multiple catalytic components with distinct "promoter" and "selector" sites to synergistically boost nitrite formation and nitrite reduction steps, respectively. image
引用
收藏
页码：245 / 269
页数：25
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