Magnetic Nanoparticles with Fe-N and Fe-C Cores and Carbon Shells Synthesized at High Pressures

Nanoparticles of iron carbides and nitrides enclosed in graphite shells were obtained at 2 divided by 8 GPa pressures and temperatures of around 800 degrees C from ferrocene and ferrocene-melamine mixture. The average core-shell particle size was below 60 nm. The graphite-like shells over the iron nitride cores were built of concentric graphene layers packed in a rhombohedral shape. It was found that at a pressure of 4 GPa and temperature of 800 degrees C, the stability of the nanoscale phases increases in a Fe7C3 > Fe3C > Fe3N1+x sequence and at 8 GPa in a Fe3C > Fe7C3 > Fe3N1+x sequence. At pressures of 2 divided by 8 GPa and temperatures up to 1600 degrees C, iron nitride Fe3N1+x is more stable than iron carbides. At 8 GPa and 1600 degrees C, the average particle size of iron nitride increased to 0.5 divided by 1 mu m, while simultaneously formed free carbon particles had the shape of graphite discs with a size of 1 divided by 2 mu m. Structural refinement of the iron nitride using the Rietveld method gave the best result for the space group P6(3)22. The refined composition of the samples obtained from a mixture of ferrocene and melamine at 8 GPa/800 degrees C corresponded to Fe3N1.208, and at 8 GPa/1650 degrees C to Fe3N1.259. The iron nitride core-shell nanoparticles exhibited magnetic behavior. Specific magnetization at 7.5 kOe of pure Fe3N1.208 was estimated to be 70 emu/g. Compared to other methods, the high-pressure method allows easy synthesis of the iron nitride cores inside pure carbon shells and control of the particle size. And in general, pressure is a good tool for modifying the phase and chemical composition of the iron-containing cores.