Treatment of Uranium-Contaminated Ground Water Using Adsorption Technology via Novel Mesoporous Silica Nanoparticles

被引:5
作者
Alshammari, Abdulmalik S. [1 ]
Almeataq, Mohammed S. [2 ]
Basfar, Ahmed A. [1 ,3 ]
机构
[1] King Saud Univ, Coll Engn, MSc Nucl Engn Program, POB 11495, Riyadh, Saudi Arabia
[2] King Abdulaziz City Sci & Technol, Nucl Technol Inst, POB 11442, Riyadh, Saudi Arabia
[3] King Saud Univ, Coll Engn, Mech Engn Dept, POB 11495, Riyadh, Saudi Arabia
关键词
uranium removal; mesoporous silica nanoparticles; adsorption; ground water; ground water treatment; uranium recycling; decontamination; EXTRACTION; SORPTION; REMOVAL; ACID;
D O I
10.3390/molecules28155642
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Contamination of underground water by uranium (U) and other heavy metals is a growing concern. Mesoporous silica nanoparticles (MSNs) have shown great potential as an adsorbent material for heavy metal removal. This study synthesized a novel MSN using surface-initiated atom transfer radical polymerization (SI-ATRP) and evaluated its effectiveness for removing uranium from aqueous solutions under different conditions. The particle size was reduced to 150-240 nm to enhance adsorption. Fourier transform infrared characterization and thermogravimetric analysis confirmed successful synthesis and modification. Results showed that the MSN adsorbent was highly effective in removing U, with a removal rate of 85.35% at 120 min. Temperature had a significant impact, with the highest removal rate of 96.7% achieved at 25 & DEG;C and a U concentration of 10 ppm. The highest removal rate of 91.89% was achieved at a pH of 6 and a U concentration of 50 ppm. The highest removal rate of 95.16% was achieved at 25 mg and a U concentration of 50 ppm at room temperature for 60 min. The MSNs also showed a 58.27% removal rate in a mixture solution at room temperature for 60 min. This study demonstrates the effectiveness of the MSN adsorbent for removing U under different conditions.
引用
收藏
页数:18
相关论文
共 29 条
[1]   Uranium extraction by sulfonated mesoporous silica derived from blast furnace slag [J].
Abd El-Magied, Mahmoud O. ;
Dhmees, Abdelghaffar S. ;
Abd El-Hamid, Abd Allah M. ;
Eldesouky, Ekramy M. .
JOURNAL OF NUCLEAR MATERIALS, 2018, 509 :295-304
[2]   Evaluation of the Adsorption Efficiency of Glycine-, Iminodiacetic Acid -, and Amino Propyl-Functionalized Silica Nanoparticles for the Removal of Potentially Toxic Elements from Contaminated Water Solution [J].
Alswieleh, Abdullah M. ;
Albahar, Hajar Y. ;
Alfawaz, Amal M. ;
Alsilme, Abdulilah S. ;
Beagan, Abeer M. ;
Alsalme, Ali M. ;
Almeataq, Mohammed S. ;
Alshahrani, Ahmed ;
Alotaibi, Khalid M. .
JOURNAL OF NANOMATERIALS, 2021, 2021
[3]   Surface modification of pH-responsive poly(2-(tert-butylamino)ethyl methacrylate) brushes grafted on mesoporous silica nanoparticles [J].
Alswieleh, Abdullah M. ;
Alshahrani, Mufleh M. ;
Alzahrani, Khalid E. ;
Alghamdi, Hamdan S. ;
Niazy, Abdurahman A. ;
Alsilme, Abdulilah S. ;
Beagan, Abeer M. ;
Alsheheri, Bayan M. ;
Alghamdi, Abdulaziz A. ;
Almeataq, Mohammed S. .
DESIGNED MONOMERS AND POLYMERS, 2019, 22 (01) :226-235
[4]   Pyridine-, thiol- and amine-functionalized mesoporous silicas for adsorptive removal of pharmaceuticals [J].
Barczak, Mariusz ;
Dobrowolski, Ryszard ;
Borowski, Piotr ;
Giannakoudakis, Dimitrios A. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2020, 299
[5]   Functionalization of mesoporous silica surface with carboxylic groups by Meldrum's acid and its application for sorption of proteins [J].
Barczak, Mariusz .
JOURNAL OF POROUS MATERIALS, 2019, 26 (01) :291-300
[6]   A review of potential remediation techniques for uranium(VI) ion retrieval from contaminated aqueous environment [J].
Bhalara, Parth D. ;
Punetha, Deepesh ;
Balasubramanian, K. .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2014, 2 (03) :1621-1634
[7]   Comparative study of humic acids flocculation with chitosan hydrochloride and chitosan glutamate [J].
Bratskaya, S ;
Schwarz, S ;
Chervonetsky, D .
WATER RESEARCH, 2004, 38 (12) :2955-2961
[8]   Polyamine and amidoxime groups modified bifunctional polyacrylonitrile-based ion exchange fibers for highly efficient extraction of U(VI) from real uranium mine water [J].
Cheng, Yanxia ;
He, Ping ;
Dong, Faqin ;
Nie, Xiaoqin ;
Ding, Congcong ;
Wang, Shuai ;
Zhang, Ying ;
Liu, Huanhuan ;
Zhou, Shiping .
CHEMICAL ENGINEERING JOURNAL, 2019, 367 :198-207
[9]   Recent Developments in Chitosan-Based Adsorbents for the Removal of Pollutants from Aqueous Environments [J].
da Silva Alves, Daniele C. ;
Healy, Bronach ;
Pinto, Luiz A. de Almeida ;
Cadaval, Tito R. Sant'Anna, Jr. ;
Breslin, Carmel B. .
MOLECULES, 2021, 26 (03)
[10]   Effects of Impregnated Amidophosphonate Ligand Concentration on the Uranium Extraction Behavior of Mesoporous Silica [J].
Dressler, Aline ;
Leydier, Antoine ;
Grandjean, Agnes .
MOLECULES, 2022, 27 (14)