Comparative Characteristics of the Nearest Environment Structures of Metal Ions in Water and Acetonitrile (A Review)

被引：0

作者：

Smirnov, P. R. ^{[1
]}

机构：

[1] Russian Acad Sci, GA Krestov Inst Solut Chem, Ivanovo 153045, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / 03期

关键词：

electrolyte solutions; structure; coordination number; ABSORPTION FINE-STRUCTURE; X-RAY-DIFFRACTION; AQUEOUS-SOLUTIONS; SOLVATION STRUCTURE; HYDRATION STRUCTURE; MOLECULAR-DYNAMICS; NEUTRON-DIFFRACTION; DIMETHYL-SULFOXIDE; COMPLEX-FORMATION; LITHIUM BROMIDE;

D O I：

10.1134/S1070363223030143

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The published data of various methods on the structural characteristics of the nearest environment of some monatomic inorganic cations in aqueous solutions and in acetonitrile under standard conditions are summarized. The structures of the first solvation shells of cations in these solvents have been compared quantitatively. It is suggested that for these systems, the structure of solvation shells of cations are independent of the solvent, and is determined only by the physicochemical nature of the ions.

引用

页码：575 / 585

页数：11

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