Synergistic improvement of mechanical properties and electrical conductivity of Cu-Fe alloys by rare earth metals Sc and Y addition

被引:11
作者
Yu, Xiangyu [1 ]
Ren, Jiawei [1 ]
Gu, Kunhui [1 ]
Zhu, Qinwen [1 ]
Cai, Hanyu [1 ]
Zheng, Liangyu [2 ]
Qiu, Wenting [1 ,2 ]
Chao, Guohui [2 ]
Gong, Shen [1 ,3 ]
机构
[1] Cent South Univ, Sch Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China
[2] Ningbo Jintian Copper Grp Co LTD, Ningbo 315034, Peoples R China
[3] State Key Lab Powder Met, Changsha 410083, Peoples R China
基金
中国国家自然科学基金;
关键词
Cu -Fe alloys; Rare earth metals Y; Rare earth metals Sc; High strength; High conductivity;
D O I
10.1016/j.jallcom.2024.173569
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cu-4.44Fe-0.26Cr-0.4Si-0.29Mg (CFCSM) alloy and Cu-4.73Fe-0.3Cr-0.38Si-0.28Mg-0.2Sc-0.24Y (CFCSM-Re) alloy were designed. After a series of thermos-mechanical treatment, the alloy has excellent overall properties. The CFCSM-Re alloy had an electrical conductivity of 65%IACS, a yield strength of 552 MPa, a tensile strength of 634 MPa and an elongation of 8.12%. The mechanical properties and electrical conductivity of the alloy were improved by the joint addition of Sc and Y. In comparison with the CFCSM alloy, the conductivity, yield strength, and tensile strength of CFCSM-Re alloy have increased by 0.8% IACS, 124 MPa and 116 MPa, respectively. In CFCSM-Re alloy, dual-scale (Fe, Cr)3Si phase and micron scale Cu(Y, Sc) phase were successfully constructed. CFCSM-Re alloys were strengthened by precipitates, which contributed approximately 50% of total strength. Adding Sc and Y inhibited the alloy's softening during annealing treatment, resulting in the alloy having high conductivity, high strength, and high elongation. The combined addition of Y and Sc atoms tended to be distributed in positions including vacancy, dislocation, grain boundary and phase interface. Rare earth metals atoms inhibited the movement of dislocations, rotation of grain boundaries and coarsening of precipitates thus endowing CFCSM-Re alloys with excellent strength, elongation and conductivity.
引用
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页数:13
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