Investigating temperature change rate and pore confinement effect on thermal properties of phase change materials for de-icing and low-temperature applications in cementitious composites

Incorporation techniques of phase change materials (PCM) in cementitious composites have a significant influence on thermal properties. This study investigated the thermal behavior of low-temperature PCM when subjected to varying temperature change rates and pore confinement inside the porous network of lightweight aggregates (LWA) and encapsulation using melamine-formaldehyde-based polymer. Three categories of thermal energy storage (TES) specimens were prepared: (i) Bulk PCM (i.e., liquid PCM), (ii) micro-encapsulated PCM (MPCM), and (iii) four different LWAs infused with PCM (PCM-LWA). The thermal properties of small-scale individual TES specimens were analyzed using a low-temperature differential scanning calorimeter (LT-DSC) to evaluate the effect of ramp rates. Dynamic vapor sorption (DVS) analysis was utilized to characterize the pore structure of LWAs. LT-DSC results show that undercooling of the PCM significantly increases with the rise in ramp rate for all the specimens; temperature change rate affects the nucleation and crystallization growth process during the phase transition. Pore structure characterization of LWAs indicates that the majority of the pores (> 92 %) were larger than 17.3 nm (i.e., macropores). Confined liquid properties are subjected to modification due to interaction with the confining surfaces, as explained by Gibbs-Thomson theory. PCM incorporated in the LWA porous network experienced variable degree of supercooling during phase transition; magnitude of confinement pressure is dependent on the pore diameter, structure, and tortuosity. Experimental evidence suggested that PCM-LWA will exhibit gradual expulsion of enthalpy of fusion over a larger temperature range (i.e., similar to-5 degrees C to 4.28 degrees C) in comparison to MPCM (i.e., similar to 4.28 degrees C).