Long-term stress crack resistance of HDPE fusion seams aged at 85?C in synthetic leachate

The stress crack resistance (SCR) and standard oxidative induction time (Std-OIT) reduction of high-density polyethylene (HDPE) geomembrane (GMB) fusion seams is examined for a 12-year old 1.5 mm HDPE GMB when welded using nine welding parameter combinations. The GMB experienced a decrease in Std-OIT from 135 to 87 min between manufacturing and welding. Welding did not significantly decrease the Std-OIT in the heat-affected zone (HAZs). In general, individual seam SCR failure times fell between the notched and unnotched sheet, with adhered squeeze-out bead seams exhibiting individual failure times closer to the notched sheet and an average time until nominal failure (tNF) similar to 21%-35% shorter than the unnotched sheet. Differences in tNF are attributed to residual stresses and (or) accelerated craze formation in seams with adhered squeeze-out beads. Non-adhered squeeze-out seams exhibited a slower tNF similar to that of the unnotched sheet, indicating a seam tNF less than that of the sheet may not be intrinsic to all HDPE fusion seams. High sheet temperatures at the time of welding and higher heat-applied welding parameters are thought to increase the likelihood of squeeze-out bead adherence. This paper shows that squeeze-out adherence can have a deleterious effect on seam SCR.