Intercalation behavior of spiro-bipyrrolidinium cation into graphite electrodes from ethylene carbonate

被引：6
作者：
Qi, Jiaxing [1 ,2 ]
Gao, Jichao [3 ]
Wang, Ying [4 ]
Yoshio, Masaki [5 ]
Wang, Hongyu [1 ,2 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
[2] Univ Sci & Technol China, Sch Appl Chem & Engn, Hefei 230026, Peoples R China
[3] Linyi Univ, Sch Chem & Chem Engn, Linyi 276000, Peoples R China
[4] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
[5] Saga Univ, Adv Res Ctr, 1341 Yoga Machi, Saga 8400047, Japan
来源：
CHINESE CHEMICAL LETTERS | 2023年 / 34卷 / 04期
基金：
中国国家自然科学基金;
关键词：
Spiro-(1; 1 ' )-bipyrrolidinium; Ethylene carbonate; Graphite intercalation compounds; Intercalated gallery height; Solvation; In situ XRD;
D O I：
10.1016/j.cclet.2022.04.073
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The intercalation behavior of spiro-(1,1 ' )-bipyrrolidinium cation (SBP + ) into graphite electrode from spiro(1,1 ' )-bipyrrolidinium tetrafluoroborate-ethylene carbonate (SBPBF 4 -EC) solutions is investigated by conventional electrochemical tests and in situ X-ray diffraction measurements. Two kinds of graphite intercalation compounds (GICs) with discrete characteristic intercalated gallery heights (IGHs) ( ca. 0.95 and 0.75 nm) can be obtained with varying the salt concentration. The effect of graphite type is also addressed. (c) 2023 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.
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页数：3
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