Luminescence study of NaMgF3:Ho and NaMgF3:Er: X-ray induced reduction Ho3+→ Ho2+

被引：1

作者：

Schuyt, J. J. ^{[1
]}

Williams, G. V. M. ^{[2
]}

Chong, S. V. ^{[1
]}

机构：

[1] Victoria Univ Wellington, Robinson Res Inst, POB 33436, Lower Hutt 5046, New Zealand

[2] Victoria Univ Wellington, SCPS, MacDiarmid Inst Adv Mat & Nanotechnol, POB 600, Wellington 6140, New Zealand

来源：

JOURNAL OF LUMINESCENCE | 2023年 / 255卷

关键词：

NaMgF3; Radiophotoluminescence; Luminescence; Holmium; Erbium; RARE-EARTH IONS; DIVALENT DYSPROSIUM; TEMPERATURE SENSOR; ENERGY-LEVELS; SPECTRA; CONVERSION; EMISSION; LASER; EU2+; NANOPARTICLES;

D O I：

10.1016/j.jlumin.2022.119595

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

X-ray induced reduction Ho3+ -> Ho2+ was observed in polycrystalline samples of NaMgF3:Ho. Prior to irradi-ation, only luminescence arising from 4f10 <-> 4f10 transitions of Ho3+ was observed. After irradiation, excitation bands arising from 4f11 -> 4f10(5IJ)5d1 transitions of Ho2+ were observed in the visible spectral region, and a corresponding 4f11(4I13/2) -> 4f11(4I15/2) emission was observed that peaked in the infrared at 1808 nm. The emissions of Ho3+ were compared with those of Dy2+, and the emissions of Ho2+ were compared with those of Er3+, in order to calculate the isoelectronic compression factors xi(4f10) = 1.17 and xi(4f11) = 1.18 for the isoelectronic Ln3+/Ln2+ pairs in the NaMgF3 host. The Ho reduction was reversible, where continuous stimu-lation with 360 nm light released trapped electrons such that Ho2+ -> Ho3+. This optically reversible Ho2+ <-> Ho3+ conversion may find applications in radiation sensing and optical data storage.

引用

页数：6

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