Reactions of phenol and its derivatives with levoglucosenone

被引：1

作者：

Faizullina, Liliya Kh. ^{[1
]}

Karamysheva, Liliya Sh. ^{[1
]}

Khalilova, Yuliya A. ^{[1
]}

Salikhov, Shamil M. ^{[1
]}

Valeev, Farid A. ^{[1
]}

机构：

[1] Russian Acad Sci, Ufa Inst Chem, Ufa Fed Res Ctr, 71 Oktyabrya Ave, Ufa 450054, Russia

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2023年 / 59卷 / 4-5期

关键词：

levoglucosenone; phenol; resorcinol; antioxidant activity; electrophilic substitution; MICHAEL ADDUCTS; CONDENSATION; CHROMENES;

D O I：

10.1007/s10593-023-03190-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The effect of hydroxy-, methyl-, and benzyloxy substituents in the corresponding phenol derivatives on the result of the Michael addition to levoglucosenone in the presence of AlCl3 or FeCl3 was studied. The reaction of phenols containing hydroxyl and methyl groups in the ortho position with levoglucosenone concludes with spontaneous ketalization of the carbohydrate keto group. The obtained compounds are promising in terms of studying their structure-activity relationship.

引用

页码：254 / 259

页数：6

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