Kanatzidisite: A Natural Compound with Distinctive van der Waals Heterolayered Architecture

被引：5

作者：

Bindi, Luca ^{[7
]}

Zhou, Xiuquan ^{[1
]}

Deng, Tianqi ^{[2
,3
,4
,5
]}

Li, Zhi ^{[6
]}

Wolverton, Christopher ^{[6
]}

机构：

[1] Argonne Natl Lab, Mat Sci Div, Lemont, IL 60439 USA

[2] Zhejiang Univ, State Key Lab Silicon & Adv Semicond Mat, Hangzhou 310027, Peoples R China

[3] Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China

[4] Zhejiang Univ, Inst Adv Semicond, ZJU Hangzhou Global Sci & Technol Innovat Ctr, Hangzhou 311215, Peoples R China

[5] Zhejiang Univ, ZJU Hangzhou Global Sci & Technol Innovat Ctr, Zhejiang Prov Key Lab Power Semicond Mat & Devices, Hangzhou 311215, Peoples R China

[6] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA

[7] Univ Firenze, Dipartimento Sci Terra, I-50121 Florence, Italy

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2023年 / 145卷 / 33期

基金：

中国国家自然科学基金;

关键词：

CRYSTAL-STRUCTURE; SUPERCONDUCTIVITY; NAGYBORZSONY; BUCKHORNITE; MINERALS;

D O I：

10.1021/jacs.3c06433

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New minerals have long been a source of inspiration forthe designand discovery. Many quantum materials, including superconductors,quantum spin liquids, and topological materials, have been unveiledthrough mineral samples with unusual structure types. In this report,we present kanatzidisite, a new naturally occurring material withformula [BiSbS3](2)[Te-2] and monoclinicsymmetry (space group of P2(1)/m) with lattice parameters a = 4.0021(5) & ANGS;, b = 3.9963(5) & ANGS;, c = 21.1009(10) & ANGS;,and & beta; = 95.392(3)& DEG;. The mineral exhibits a unique structureconsisting of alternating BiSbS3 double van der Waals layersand distorted [Te] square nets essentially forming an array of parallelzigzag Te chains. Our theoretical calculations suggest that the bandstructure of kanatzidisite may exhibit topological features characteristicof a Dirac semimetal.

引用

页码：18227 / 18232

页数：6

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