Degradation Profiles of MgO@Graphene Nanocomposite Photocatalyst for Organic and Antibiotic Pollutants: Novel Approaches

被引:0
作者
Fouda, Safaa R. [1 ]
Yehia, I. S. [2 ,3 ]
机构
[1] Menoufia Higher Inst Engn & Technol MNF HIET, Chem Engn Dept, Cairo, Egypt
[2] King Khalid Univ, Fac Sci, Dept Phys, Lab Nanosmart Mat Sci & Technol LNSMST, POB 9004, Abha, Saudi Arabia
[3] Ain Shams Univ, Fac Educ, Dept Phys, Nanosci Lab Environm & Biomed Applicat NLEBA, Cairo 11757, Egypt
关键词
MgO NPs@Graphene nanocomposites; graphene exfoliation production; photocatalytic degradation; 4-nitrophenol/streptomycin; organic and antibiotic pollutants; HYBRID NANOFIBERS; OXIDE; NANOPARTICLES; ADSORPTION; CARBON;
D O I
10.1142/S1793984424500089
中图分类号
TB3 [工程材料学]; R318.08 [生物材料学];
学科分类号
0805 ; 080501 ; 080502 ;
摘要
Streptomycin was chosen as the test species, and MgO@graphene nanocomposites were created and assessed for their catalytic activity towards the breakdown of 4-NP. As a new catalyst with strong catalytic activity and good stability, MgO@graphene was used. It was discovered that this catalyst's catalytic activity was much increased in an acidic environment. It is suggested that the degradation mechanism is caused by MgO@graphene nanocomposites reacting with dissolved oxygen. This further demonstrates the obvious significance of graphene in serving as the MgO nanocatalyst's support. XRD results indicated that the majority of G species in MgO@ (0.25 g) G more strongly interacted with the MgO surface. The doped catalyst MgO@ (0.25 g) G reached its steady state activity faster than the other catalysts. The degree of MgO@G interaction decreased in the following S-4 > S-mix > S-2 > S-3 > S-1 > S-5 > S-6 > S-o. High degradation rate constants were found, and the amounts of streptomycin and 4-nitrophenol vary exponentially over time. It was demonstrated that, in most situations, the pseudo-first-order equation fits the degradation kinetics. Hence, in degrading systems, MgO NPs@Graphene nanostructures are thought to be a very effective and promising catalyst.
引用
收藏
页数:16
相关论文
共 45 条
[31]   Environmental applications of graphene-based nanomaterials [J].
Perreault, Francois ;
de Faria, Andreia Fonseca ;
Elimelech, Menachem .
CHEMICAL SOCIETY REVIEWS, 2015, 44 (16) :5861-5896
[32]   Graphene: The New Two-Dimensional Nanomaterial [J].
Rao, C. N. R. ;
Sood, A. K. ;
Subrahmanyam, K. S. ;
Govindaraj, A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (42) :7752-7777
[33]  
Saba N., 2018, Polymer-Based Nanocomposites for Energy and Environmental Applications, P105
[34]   Optimizing the synthesis conditions of silver nanoparticles using corn starch and their catalytic reduction of 4-nitrophenol [J].
Salaheldin H.I. .
Advances in Natural Sciences: Nanoscience and Nanotechnology, 2018, 9 (02)
[35]  
Samadi S, 2017, BULL SOC R SCI LIEGE, P271, DOI [10.25518/0037-9565.6709, 10.25518/0037-9565.6709]
[36]  
School of Chemistry and Chemical Engineering Shandong University Jinan Shandong 250100 China, 2019, ENG SCI, DOI [10.30919/es8d509, 10.30919/es8d509, DOI 10.30919/ES8D509]
[37]   Comparative study of microwave and conventional methods for the preparation and optical properties of novel MgO-micro and nano-structures [J].
Selvam, N. Clament Sagaya ;
Kumar, R. Thinesh ;
Kennedy, L. John ;
Vijaya, J. Judith .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (41) :9809-9815
[38]   Bioinspired ZnO-Based Solar Photocatalysts for the Efficient Decontamination of Persistent Organic Pollutants and Hexavalent Chromium in Wastewater [J].
Serra, Albert ;
Gomez, Elvira ;
Philippe, Laetitia .
CATALYSTS, 2019, 9 (12)
[39]   Phytoassisted synthesis of magnesium oxide nanoparticles with Swertia chirayaita [J].
Sharma, Gaurav ;
Soni, Rajgovind ;
Jasuja, Nakuleshwar Dut .
JOURNAL OF TAIBAH UNIVERSITY FOR SCIENCE, 2017, 11 (03) :471-477
[40]  
Sheshmani S, 2013, ACTA CHIM SLOV, V60, P813