Degradation Profiles of MgO@Graphene Nanocomposite Photocatalyst for Organic and Antibiotic Pollutants: Novel Approaches

被引:0
作者
Fouda, Safaa R. [1 ]
Yehia, I. S. [2 ,3 ]
机构
[1] Menoufia Higher Inst Engn & Technol MNF HIET, Chem Engn Dept, Cairo, Egypt
[2] King Khalid Univ, Fac Sci, Dept Phys, Lab Nanosmart Mat Sci & Technol LNSMST, POB 9004, Abha, Saudi Arabia
[3] Ain Shams Univ, Fac Educ, Dept Phys, Nanosci Lab Environm & Biomed Applicat NLEBA, Cairo 11757, Egypt
关键词
MgO NPs@Graphene nanocomposites; graphene exfoliation production; photocatalytic degradation; 4-nitrophenol/streptomycin; organic and antibiotic pollutants; HYBRID NANOFIBERS; OXIDE; NANOPARTICLES; ADSORPTION; CARBON;
D O I
10.1142/S1793984424500089
中图分类号
TB3 [工程材料学]; R318.08 [生物材料学];
学科分类号
0805 ; 080501 ; 080502 ;
摘要
Streptomycin was chosen as the test species, and MgO@graphene nanocomposites were created and assessed for their catalytic activity towards the breakdown of 4-NP. As a new catalyst with strong catalytic activity and good stability, MgO@graphene was used. It was discovered that this catalyst's catalytic activity was much increased in an acidic environment. It is suggested that the degradation mechanism is caused by MgO@graphene nanocomposites reacting with dissolved oxygen. This further demonstrates the obvious significance of graphene in serving as the MgO nanocatalyst's support. XRD results indicated that the majority of G species in MgO@ (0.25 g) G more strongly interacted with the MgO surface. The doped catalyst MgO@ (0.25 g) G reached its steady state activity faster than the other catalysts. The degree of MgO@G interaction decreased in the following S-4 > S-mix > S-2 > S-3 > S-1 > S-5 > S-6 > S-o. High degradation rate constants were found, and the amounts of streptomycin and 4-nitrophenol vary exponentially over time. It was demonstrated that, in most situations, the pseudo-first-order equation fits the degradation kinetics. Hence, in degrading systems, MgO NPs@Graphene nanostructures are thought to be a very effective and promising catalyst.
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页数:16
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