Competition between the oxygen evolution reaction and the electrooxidation of alcohols on heteroatom-functionalized multi-walled carbon nanotubes-supported Ni oxide catalysts

被引：9

作者：

Morales, Eleazar Castaneda ^{[1
]}

Kazakova, Mariya A. ^{[2
]}

Selyutin, Alexander G. ^{[2
,3
]}

Golubtsov, Georgiy, V ^{[2
]}

Morales, Dulce M. ^{[1
]}

Robledo, Arturo Manzo ^{[1
]}

机构：

[1] Inst Politecn Nacl, Escuela Super Ingn Quim & Ind Extract, Lab Electroquim & Corros, Unidad Profes Adolfo Lopez Mateos, Av Inst Politecn Nacl S-N, Mexico City 07708, Mexico

[2] Boreskov Inst Catalysis SB RAS, Novosibirsk 630090, Russia

[3] Boreskov Inst Catalysis SB RAS, Synchrotron Radiat Facil SKIF, Nikolskiy Prospekt 1, Koltsov 630559, Russia

来源：

SURFACES AND INTERFACES | 2024年 / 46卷

关键词：

DEMS; Alcohol electrooxidation; Oxygen evolution reaction; Nickel oxide; Hybrid water electrolysis; Heteroatom doping; ELECTROCATALYTIC OXIDATION; METHANOL ELECTROOXIDATION; GLYCEROL OXIDATION; HIGH-ENERGY; NICKEL; NANOPARTICLES; ELECTRODE; CATHODE; SURFACE; MWCNTS;

D O I：

10.1016/j.surfin.2024.104026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hybrid water electrolysis is a prominent route for hydrogen production that circumvents issues related to the oxygen evolution reaction (OER), the anode process in conventional water electrolysis, by integrating an alternative anode reaction. Herein, samples of nickel oxide nanoparticles supported on oxygen and nitrogenfunctionalized multi-walled carbon nanotubes were evaluated as electrocatalysts for the OER and the electrooxidation of methanol (MOR), ethanol (EOR) and glycerol (GOR). The trend of overpotentials measured at a current of 0.1 mA was OER > MOR > EOR > GOR, with slightly lower overpotentials observed for the nitrogendoped sample, which is attributed to differences in nanoparticle size and distribution, support defectiveness, and nitrogen-induced electronic effects. The production of oxygen was monitored by Differential Electrochemical Mass Spectrometry (DEMS), indicating that the competition between OER and alcohol electrooxidation can be modulated by the support properties as well as by the nature and concentration of the alcohol.

引用

页数：14

共 73 条

[1] The one-pot synthesis of CuNi nanoparticles with a Ni-rich surface for the electrocatalytic methanol oxidation reaction [J].

An, Yajing ;

Ijaz, Hamza ;

Huang, Ming ;

Qu, Jianqiang ;

Hu, Shi .

DALTON TRANSACTIONS, 2020, 49 (05) :1646-1651

[2] Internal field 59Co NMR study of cobalt-iron nanoparticles during the activation of CoFe2/CaO catalyst for carbon nanotube synthesis [J].

Andreev, Andrey S. ;

Krasnikov, Dmitry V. ;

Zaikovskii, Vladimir I. ;

CherepanoVa, Svetlana V. ;

Kazakova, Mariya A. ;

Lapina, Olga B. ;

Kuznetsov, Vladimir L. ;

d'Espinose de Lacaillerie, Jean-Baptiste .

JOURNAL OF CATALYSIS, 2018, 358 :62-70

[3] Differential electrochemical mass spectrometry [J].

Baltruschat, H .

JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2004, 15 (12) :1693-1706

[4] Ethanol electro-oxidation reaction using a polycrystalline nickel electrode in alkaline media: Temperature influence and reaction mechanism [J].

Barbosa, A. F. B. ;

Oliveira, V. L. ;

van Drunen, J. ;

Tremiliosi-Filho, G. .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2015, 746 :31-38

[5]

Bard A. J., 2000, Electrochemical Methods: Fundamentals and Applications, V2nd

[6] Palladium-Based Electrocatalysts for Alcohol Oxidation in Half Cells and in Direct Alcohol Fuel Cells [J].

Bianchini, Claudio ;

Shen, Pei Kang .

CHEMICAL REVIEWS, 2009, 109 (09) :4183-4206

[7] Surface studies of hydroxylated multi-wall carbon nanotubes [J].

Bradley, Robert H. ;

Cassity, Kelby ;

Andrews, Rodney ;

Meier, Mark ;

Osbeck, Susan ;

Andreu, Aurik ;

Johnston, Colin ;

Crossley, Alison .

APPLIED SURFACE SCIENCE, 2012, 258 (11) :4835-4843

[8] From waste to value-Glycerol electrooxidation for energy conversion and chemical production [J].

Braun, Michael ;

Santana, Cassia S. ;

Garcia, Amanda C. ;

Andronescu, Corina .

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY, 2023, 41

[9] Electrocatalytic Oxidation of Glycerol Using Solid-State Synthesised Nickel Boride: Impact of Key Electrolysis Parameters on Product Selectivity [J].

Brix, Ann Cathrin ;

Morales, Dulce M. ;

Braun, Michael ;

Jambrec, Daliborka ;

Junqueira, Joao R. C. ;

Cychy, Steffen ;

Seisel, Sabine ;

Masa, Justus ;

Muhler, Martin ;

Andronescu, Corina ;

Schuhmann, Wolfgang .

CHEMELECTROCHEM, 2021, 8 (12) :2336-2342

[10] XPS Analysis of K-based Reference Compounds to Allow Reliable Studies of Solid Electrolyte Interphase in K-ion Batteries [J].

Caracciolo, Laure ;

Madec, Lenaic ;

Martinez, Herve .

ACS APPLIED ENERGY MATERIALS, 2021, 4 (10) :11693-11699

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