Interconnected Sn@SnO2 Nanoparticles as an Anode Material for Lithium-Ion Batteries

被引：14
作者：
Rodriguez, Jassiel R. [4 ,5 ]
Hamann, Henry J. [1 ]
Mitchell, Garrett M. [2 ,3 ]
Ortalan, Volkan [2 ,3 ]
Gribble, Daniel [4 ]
Xiong, Beichen [4 ]
Pol, Vilas G. [4 ]
Ramachandran, P. Veeraraghavan [1 ]
机构：
[1] Purdue Univ, Herbert C Brown Ctr Borane Res, Dept Chem, W Lafayette, IN 47907 USA
[2] Purdue Univ, Sch Mat Engn, W Lafayette, IN 47907 USA
[3] Purdue Univ, Birck Nanotechnol Ctr, W Lafayette, IN 47907 USA
[4] Purdue Univ, Davidson Sch Chem Engn, W Lafayette, IN 47907 USA
[5] Ctr Invest Cient & Educ Super Ensenada, Ensenada 22860, BC, Mexico
来源：
ACS APPLIED NANO MATERIALS | 2023年 / 6卷 / 13期
关键词：
lithium-ion battery; ammonia-borane reduction; tin; core-shell nanoparticle; discharge-chargecapacity; TIN; CHALCOGENIDES; PERFORMANCE; REDUCTION; COMPOSITE; STORAGE; ALLOY;
D O I：
10.1021/acsanm.3c00854
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Ammonia-borane reduction of tin (II) chloride was utilizedto preparecustomized and interconnected Sn@SnO2 core-shellnanoparticles. Remarkably, the Sn@SnO2-based electrodedelivered a reversible capacity of 722 mAh g(-1) at0.5 C after 200 cycles with a Coulombic efficiency of similar to 99%.Also, this electrode exhibited a high rate capability (564 mAh g(-1) at 1.0 C), low charge transfer resistance (44.7 omega),and reasonable electrode polarization (146 mV vs Li/Li+), which led to a high capacity retention (similar to 94%). Additionally,the kinetics of Li-ion storage of the sample revealed that the capacitance contribution plays a main roleat fast C-rates. This new nanoarchitecture is promising for stablelithium-ion storage because of the presence of voids and a SnO2 shell in the interconnected Sn@SnO2 nanoparticles,in which the cavities mitigate its volume expansion upon cycling;meanwhile, the SnO2 layer increases its capacity.
引用
收藏
页码：11070 / 11076
页数：7
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