Cobalt-catalyzed amination of aziridines and azetidines toward 1,2-and 1,3-diamines

被引：2

作者：

Cheng, Ling-Chao ^{[1
]}

Wang, Zhihua ^{[1
]}

He, Xinglei ^{[1
]}

Liang, Wangfu ^{[1
]}

Ye, Ke-Yin ^{[1
]}

机构：

[1] Fuzhou Univ, Fujian Prov Univ, Coll Chem, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2024年 / 22卷 / 13期

基金：

中国国家自然科学基金;

关键词：

ALKENE DIAMINATION; CONJUGATED DIENES; VICINAL DIAMINES; FACILE ACCESS; RING; PALLADIUM; DIFUNCTIONALIZATION; 1,2-DIAMINATION; ORGANOCATALYSIS; ACTIVATION;

D O I：

10.1039/d4ob00168k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diamines play important roles in synthetic organic chemistry and thus facilitate life and materials sciences. Herein we report a cobalt-catalyzed ring opening, nucleophilic amination of aziridines and azetidines with N-fluorosulfonamides toward a wide range of 1,2- and 1,3-diamine derivatives in moderate to good yields under mild conditions. A cobalt-catalyzed ring opening, nucleophilic amination of aziridines and azetidines with N-fluorosulfonamides has been established toward a wide range of 1,2- and 1,3-diamine derivatives in moderate to good yields under mild conditions.

引用

页码：2554 / 2557

页数：4

共 66 条

[1] Immunomodulatory drugs in the treatment of multiple myeloma [J].