Preparation and photochemical properties of cyclometalated ruthenium(II) nitrosyl complexes

被引：0
|
作者：
Wang Yi-Rong [1 ]
Li Zhen [1 ]
Wu Yu-Hao [1 ]
Li Xiang-Hong [1 ]
Zhang Bing-Guang [1 ]
机构：
[1] South Cent Minzu Univ, Coll Chem & Mat Sci, Wuhan 430074, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 39卷 / 05期
关键词：
cyclometalated ruthenium complex; ruthenium nitrosyl complex; NO; 2-phenylpyridine; photolysis reaction; NITRIC-OXIDE; NO; LIGHT; RELEASE; DELIVERY;
D O I：
10.11862/CJIC.2023.059
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Complex 1 with 2-(4-methylphenyl)pyridine as C, N-ligand was used to react with NOBF4 under different conditions to afford two cyclometalated ruthenium(II) nitrosyl complexes 2 and 3 in high yields. Herein, increasing temperature and aerobic conditions were favored by the generation of 3. NMR, MS, IR, and single-crystal X-ray structure analysis showed that these two nitrosyl complexes have {Ru-II-NO+} characteristics. This was further confirmed by electrochemistry and UV-Vis absorption spectra. Subsequently, the photolyzed product of ruthenium nitrosyl complex 2 was separated and characterized by NMR and MS spectra. The result showed that such nitrosyl complexes could give a release of NO by the breakage of Ru-NO under the light, along with Ru(II) as the oxidation state.
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页码：867 / 873
页数：7
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  • [11] Photocleavage of Coordinated NO under Visible Light from Two Different Classes of Organometallic Ruthenium Nitrosyl Complexes: Reversible Binding of Phenolato Function
    Ghosh, Kaushik
    Kumar, Sushil
    Kumar, Rajan
    Singh, Udai P.
    Goel, Nidhi
    [J]. ORGANOMETALLICS, 2011, 30 (09) : 2498 - 2505
  • [12] Near-IR light-induced photorelease of nitric oxide (NO) on ruthenium nitrosyl complexes: formation, reactivity, and biological effects
    Giri, Bishnubasu
    Saini, Taruna
    Kumbhakar, Sadananda
    Selvan, Kalai K.
    Muley, Arabinda
    Misra, Ashish
    Maji, Somnath
    [J]. DALTON TRANSACTIONS, 2020, 49 (31) : 10772 - 10785
  • [13] Cyclometalated ruthenium chloro and nitrosyl complexes
    Hadadzadeh, H
    DeRosa, MC
    Yap, GPA
    Rezvani, AR
    Crutchley, RJ
    [J]. INORGANIC CHEMISTRY, 2002, 41 (24) : 6521 - 6526
  • [14] A Water-Soluble, Green-Light Triggered, and Photo-Calibrated Nitric Oxide Donor for Biological Applications
    He, Haihong
    Xia, Yang
    Qi, Yingxue
    Wang, Hong-Yin
    Wang, Zhuang
    Bao, Jianming
    Zhang, Ziqian
    Wu, Fu-Gen
    Wang, Haolu
    Chen, Daijie
    Yang, Dahai
    Liang, Xiaowen
    Chen, Jinquan
    Zhou, Shengmin
    Liang, Xin
    Qian, Xuhong
    Yang, Youjun
    [J]. BIOCONJUGATE CHEMISTRY, 2018, 29 (04) : 1194 - 1198
  • [15] Photoinduced Nitric Oxide Release from a Hindered Nitrobenzene Derivative by Two-Photon Excitation
    Hishikawa, Kazuhiro
    Nakagawa, Hidehiko
    Furuta, Toshiaki
    Fukuhara, Kiyoshi
    Tsumoto, Hiroki
    Suzuki, Takayoshi
    Miyata, Naoki
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) : 7488 - +
  • [16] Organometallic Ruthenium Nitrosyl Obtained by C-H Bond Activation - Photoinduced Delivery of Nitric Oxide and NO-Mediated Antiproliferation Activity Studies
    Kumar, Rajan
    Yadav, Anjlika
    Ratnam, Anand
    Kumar, Sushil
    Bala, Manju
    Sur, Debpali
    Narang, Shikha
    Singh, Udai P.
    Mandal, Prabhat K.
    Ghosh, Kaushik
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (45) : 5334 - 5343
  • [17] A ruthenium-nitrosyl-functionalized nanoplatform for the targeting of liver cancer cells and NIR-light-controlled delivery of nitric oxide combined with photothermal therapy
    Li, Yan-Hui
    Guo, Min
    Shi, Shu-Wen
    Zhang, Qian-Ling
    Yang, Shi-Ping
    Liu, Jin-Gang
    [J]. JOURNAL OF MATERIALS CHEMISTRY B, 2017, 5 (38) : 7831 - 7838
  • [18] Orthometalation of Dibenzo[1,2]quinoxaline with Ruthenium(II/III), Osmium(II/III/IV), and Rhodium(III) Ions and Orthometalated [RuNO]6/7 Derivatives
    Maity, Suvendu
    Kundu, Suman
    Roy, Amit Saha
    Weyhermueller, Thomas
    Ghosh, Prasanta
    [J]. INORGANIC CHEMISTRY, 2015, 54 (04) : 1384 - 1394
  • [19] Photosensitized NO release from water-soluble nanoparticle assemblies
    Neuman, Daniel
    Ostrowski, Alexis D.
    Absalonson, Ryan O.
    Strouse, Geoffrey F.
    Ford, Peter C.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (14) : 4146 - +
  • [20] Metal complexes as photochemical nitric oxide precursors: Potential applications in the treatment of tumors
    Ostrowski, Alexis D.
    Ford, Peter C.
    [J]. DALTON TRANSACTIONS, 2009, (48) : 10660 - 10669
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