Preparation and plasticizing mechanism of deep eutectic solvent/lignin plasticized chitosan films

Chitosan (CS) is a natural biopolymer from crab shells known for its biocompatibility and biodegradability; however, CS films are extremely rigid, limiting their applications. In this study, CS composite films were pre-pared based on the selective dissolution of lignin by deep eutectic solvents (DES), and the toughening effect of this DES/lignin on a CS film substrate was examined, along with its corresponding mechanism. The addition of DES/lignin effectively increased the plasticity of the CS film, giving a maximum elongation at break of 62.6 % for the plasticized film, which is 12.5 times that of the CS film. Fourier transform infrared spectroscopy and nuclear magnetic resonance analyses showed that molecules in the DES/lignin complex interacted with CS to break the hydrogen bonds between the CS molecules; simultaneously, each molecule recombined with the CS molecules via hydrogen bonding. Thus, the rigidity of the CS molecular chain was weakened to achieve a plasticized CS film, thereby demonstrating the ability of DES/regenerated lignin to improve the toughness of CS films, which pro-vides a reference for modifying plasticity and could lead to the broader utilization of CS films.