An Anionic Porous Indium-Organic Framework with Nitrogen-Rich Linker for Efficient and Selective Removal of Trace Cationic Dyes

Metal-organic frameworks (MOFs) with porosity and functional adjustability have great potential for the removal of organic dyes in the wastewater. Herein, an anionic porous metal-organic framework (MOFs) [Me2NH2](2)In-2[(TATAB)(4)(DMF)(4)]& BULL;(DMF)(4)(H2O)(4) (HDU-1) was synthesized, which is constructed from a [In(OOC)(4)](-) cluster and a nitrogen-rich linker H(3)TATAB (4,4 & PRIME;,4 & DPRIME;-s-triazine-1,3,5-triyltri-p-aminobenzoic acid). The negatively charged [In(OOC)(4)](-) cluster and uncoordinated -COOH on the linker result in one unit cell of HDU-1 having 8 negative sites. The zeta potential of -20.8 mV dispersed in pure water also shows that HDU-1 possesses negatively charged surface potential. The high electronegativity, water stability, and porosity of HDU-1 can facilitate the ion-exchange and Coulombic interaction. As expected, the HDU-1 exhibits high selectivity and removal rates towards trace cationic dyes with suitable size, such as methylene blue (MB) (96%), Brilliant green (BG) (99.3%), and Victoria blue B (VB) (93.6%).