Design and synthesis of dinuclear cobalt(ii) complexes derived from strong π-acidic ligands: crystal structure and studies on the oxidation of sp3 C-H bonds

被引：4

作者：

Singh, Anshu ^{[1
]}

Boro, Bishal ^{[1
]}

Maji, Ankur ^{[1
]}

Singh, Ovender ^{[1
]}

Singh, Sain ^{[1
]}

Singh, Udai P. ^{[1
]}

Ghosh, Kaushik ^{[1
,2
]}

机构：

[1] Indian Inst Technol Roorke, Dept Chem, Roorkee 247667, Uttarakhand, India

[2] Indian Inst Technol Roorkee, Biosci & Bioengn, Roorkee 247667, Uttarakhand, India

来源：

NEW JOURNAL OF CHEMISTRY | 2023年 / 47卷 / 18期

关键词：

CATALYTIC-OXIDATION; AEROBIC OXIDATION; FUNCTIONALIZATION; HYDROFORMYLATION; MANGANESE(II); REACTIVITY; EFFICIENT; IRON; OPPORTUNITIES; SELECTIVITY;

D O I：

10.1039/d3nj00128h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, cobalt complexes 1 and 2 were synthesized from ligands L-1 (1,2-bis(2-phenyl-2-(pyridin-2-yl)hydrazineylidene)ethane) and L-2 (1,2-bis(2-(pyridin-2-yl)hydrazineylidene)ethane) in moderate yields. These complexes were characterized by UV-visible, IR and ESI-MS spectroscopic studies. The molecular structure of complex 1 was determined by X-ray crystallography. Complexes 1 and 2 were employed as catalysts for the oxidation of sp(3) C-H bonds. A total of 12 substrates were investigated for the oxidation of benzylic and aliphatic sp(3) C-H bonds. A reaction pathway was proposed and possible reactive intermediate species was successfully characterized by ESI-MS spectroscopic studies.

引用

页码：8951 / 8959

页数：9

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