Recent advances in zinc-air batteries: self-standing inorganic nanoporous metal films as air cathodes

Zinc-air batteries (ZABs) have promising prospects as next-generation electrochemical energy systems due to their high safety, high power density, environmental friendliness, and low cost. However, the air cathodes used in ZABs still face many challenges, such as the low catalytic activity and poor stability of carbon-based materials at high current density/voltage. To achieve high activity and stability of rechargeable ZABs, chemically and electrochemically stable air cathodes with bifunctional oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) activity, fast reaction rate with low platinum group metal (PGM) loading or PGM-free materials are required, which are difficult to achieve with common electrocatalysts. Meanwhile, inorganic nanoporous metal films (INMFs) have many advantages as self-standing air cathodes, such as high activity and stability for both the ORR/OER under highly alkaline conditions. The high surface area, three-dimensional channels, and porous structure with controllable crystal growth facet/direction make INMFs an ideal candidate as air cathodes for ZABs. In this review, we first revisit some critical descriptors to assess the performance of ZABs, and recommend the standard test and reported manner. We then summarize the recent progress of low-Pt, low-Pd, and PGM-free-based materials as air cathodes with low/non-PGM loading for rechargeable ZABs. The structure-composition-performance relationship between INMFs and ZABs is discussed in-depth. Finally, we provide our perspectives on the further development of INMFs towards rechargeable ZABs, as well as current issues that need to be addressed. This work will not only attract researchers' attention and guide them to assess and report the performance of ZABs more accurately, but also stimulate more innovative strategies to drive the practical application of INMFS for ZABs and other energy-related technologies.