Crystal structure of 2-(morpholino)ethylammonium picrate monohydrate

被引：4

作者：

Chidambaranathan, Balasubramanian ^{[1
]}

Sivaraj, Settu ^{[1
]}

Selvakumar, Shanmugam ^{[1
]}

机构：

[1] Govt Arts Coll Men, PG & Res Dept Phys, Chennai 600035, Tamil Nadu, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷

关键词：

single-crystal X-ray study; morpholine; hydrogen bond; IR; NMR; Hirshfeld surface analysis; INTERMOLECULAR INTERACTIONS; QUANTITATIVE-ANALYSIS; MOLECULAR-STRUCTURES; GRAPH-SET; X-RAY;

D O I：

10.1107/S2056989022011409

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C6H15N2O+ .C6H2N3O7- .H2O, was synthesized via slow evaporation of an aqueous solution of picric acid with the substituted morpholine base and crystallized with one cation (C6H15N2O)(+), one anion (C6H2N3O7)(-) and a water molecule in the asymmetric unit. The morpholine ring in the cation adopts a chair conformation. The structure is stabilized by C-H...O, O-H...O, O-H...N and N-H...O hydrogen-bonding interactions and pi-pi stacking. The intermolecular interactions of the synthesized compound were quantified by Hirshfeld surface analysis.

引用

页码：8 / +

页数：11

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