Synthesis of poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) block copolymers

被引：3
|
作者：
Xiao-li ZHAN1
机构：
来源：
Journal of Zhejiang University(Science A:An International Applied Physics & Engineering Journal) | 2008年 / 09期
基金：
中国国家自然科学基金;
关键词：
Block copolymers; Polysiloxanes; Fluoropolymers; Synthesis; Polyethyleneoxide;
D O I：
暂无
中图分类号：
O631.3 [高聚物的化学性质];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of new amphiphilic poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) (PMTFPS-b-PEO) diblock copolymers with different ratios of hydrophobic segment to hydrophilic segment were prepared by coupling reactions of end-functional PMTFPS and PEO homopolymers. Copolymers were shown to be well defined and narrow molecular weight distribution (MWD) (1.07~1.3) by characterizations such as gel permeation chromatography (GPC) and 1H-nudear magnetic resonance (1H-NMR).
引用
收藏
页码：1304 / 1308
页数：5
相关论文
共 50 条
  • [11] Poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide)-g-poly(vinyl pyrrolidone):: Synthesis and characterization
    Zhang, Y
    Lam, YM
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 285 (01) : 80 - 85
  • [12] Synthesis and thermal decomposition kinetics of poly(methyl methacrylate)-b-poly(styrene) block copolymers
    Guan, Xinghua
    Ma, Xiaoyan
    Zhou, Hualong
    Chen, Fang
    Li, Zhiguang
    JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS, 2017, 30 (05) : 691 - 706
  • [13] Syntheses of well-defined poly(siloxane)-b-poly(styrene) and poly(norbomene)-b-poly(styrene) block copolymers using functional alkoxyamines
    Miura, Y
    Sakai, Y
    Taniguchi, I
    POLYMER, 2003, 44 (03) : 603 - 611
  • [14] Morphology control of poly(3-hexylthiophene)-b-poly(ethylene oxide) block copolymer by solvent blending
    He, Luze
    Pan, Shuang
    Peng, Juan
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2016, 54 (05) : 544 - 551
  • [15] Synthesis and Characterization of Poly(ε-caprolactone)-b-Poly(ethylene glycol)-b-Poly(ε-caprolactone) Triblock Copolymers with Dibutylmagnesium as Catalyst
    Wei, Zhiyong
    Liu, Lian
    Yu, Fengyun
    Wang, Pei
    Qi, Min
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 111 (01) : 429 - 436
  • [16] Synthesis and crystallizability of poly(ethylene glycol)-b-poly(ε-caprolactone)-b-poly(ethylene glycol)
    Wang, Pei
    Liu, Lian
    Qu, Chao
    Wei, Zhiyong
    Qi, Min
    JOURNAL OF CONTROLLED RELEASE, 2011, 152 : E240 - E242
  • [17] Microphase separation of poly(propylene monothiocarbonate)-b-poly (ethylene oxide) block copolymers induced by differential interactions with salt
    Cao, Xiao-Han
    Yang, Jia-Liang
    Wang, Rui-Yang
    Zhang, Xing-Hong
    Xu, Jun-Ting
    POLYMER, 2019, 180
  • [18] Synthesis of Poly(vinylidene fluoride)-b-poly(styrene sulfonate) Block Copolymers by Controlled Radical Polymerizations
    Laruelle, Gael
    Nicol, Erwan
    Ameduri, Bruno
    Tassin, Jean-Francois
    Ajellal, Noureddine
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (18) : 3960 - 3969
  • [19] Crystallization and Physical Ageing of Poly (2-vinyl pyridine)-b-poly(ethylene oxide) Diblock Copolymers
    Cordova, Miguel
    Lorenzo, Arnaldo T.
    Mueller, Alejandro J.
    Fragouli, Panagiota
    Iatrou, Hermis
    Hadjichristidis, Nikos
    MACROMOLECULAR SYMPOSIA, 2010, 287 : 101 - 106
  • [20] Synthesis and characterization of vinyl-terminated copolysiloxanes containing 3,3,3-trifluoropropyl groups
    Li, Bo
    Chen, Shuangjun
    Zhang, Jun
    POLYMER CHEMISTRY, 2012, 3 (09) : 2366 - 2376
12345