Synthesis and crystal structure of an ionic cluster {[Mo3（μ3-O）(μ-S)3（dtp）3（py）3][CdI（dtp）2]}

被引：0
|
作者：
LU
机构：
来源：
Chinese Journal of Chemistry | 1997年 / 04期
基金：
中国国家自然科学基金;
关键词：
Molybdenum; cadmium; cluster; synthesis; crystal structure;
D O I：
暂无
中图分类号：
O76 [晶体结构];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new cluster compound {[Mo3(μ3-O)(μ-S)3(dtp)3(py)3][CdI(dtp)2]} (dtp=S2P(O-was obtained from the reaction of (Mo3OS3(dtp)4(H2O)] with a CdI2-Bu4NI mixture.The molecular structure is composed of a cluster cation [Mo3OS3(dtp)3(py)3]+ and the complex anion [CdI(dtp)2]-Crystal data:Triclinic,space group P1 with cell parameters a=1.4672(7),b=1.5356(5),c=1.6806(5) nm,α=74.59(3),β=67.89(4),7=78.86(3)°,V=3.364(2) nm3,and Z=2,least-squares refinement of 8941 reflections gives a final agreement factor of R=0.052,Rw=0.065.
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页码：296 / 303
页数：8
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