Synthesis and crystal structure of an ionic cluster {[Mo3（μ3-O）(μ-S)3（dtp）3（py）3][CdI（dtp）2]}

被引：0
|
作者：
LU
机构：
来源：
Chinese Journal of Chemistry | 1997年 / 04期
基金：
中国国家自然科学基金;
关键词：
Molybdenum; cadmium; cluster; synthesis; crystal structure;
D O I：
暂无
中图分类号：
O76 [晶体结构];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new cluster compound {[Mo3(μ3-O)(μ-S)3(dtp)3(py)3][CdI(dtp)2]} (dtp=S2P(O-was obtained from the reaction of (Mo3OS3(dtp)4(H2O)] with a CdI2-Bu4NI mixture.The molecular structure is composed of a cluster cation [Mo3OS3(dtp)3(py)3]+ and the complex anion [CdI(dtp)2]-Crystal data:Triclinic,space group P1 with cell parameters a=1.4672(7),b=1.5356(5),c=1.6806(5) nm,α=74.59(3),β=67.89(4),7=78.86(3)°,V=3.364(2) nm3,and Z=2,least-squares refinement of 8941 reflections gives a final agreement factor of R=0.052,Rw=0.065.
引用
收藏
页码：296 / 303
页数：8
相关论文
共 50 条
  • [21] Solvent dependent mechanistic pathways for η-O2CCH3 substitution from the [Mo3(μ3-O)2(μ-O2CCH3)6(η-O2CCH3)3]- anion
    Houston, Jacqueline R.
    Burton, Andrew J.
    INORGANICA CHIMICA ACTA, 2013, 407 : 210 - 215
  • [22] Synthesis and Structure of a 〔Mo3S7〕3.5+ Complex〔Mo3（μ3-S）(μ2-S2)3（Et2dtc）3〕2Cl
    ZHU Hong-Ping
    LIU Qiu-Tian
    CHEN Chang-Neng
    DENG Yu-Heng(State Key Laboratory of Structural Chemistry
    结构化学, 1998, (02) : 142 - 146
  • [23] Multinuclear zinc(II) complexes with {Zn6(μ-O)6(μ3-O)2}- and {Zn5(μ-O)3(μ3-O)3}-cluster cores
    Constable, Edwin C.
    Housecroft, Catherine E.
    Zampese, Jennifer A.
    Zhang, Guoqi
    POLYHEDRON, 2012, 44 (01) : 150 - 155
  • [24] Crystal structures and 31P NMR spectra of two trinuclear molybdenum clusters coordinated by p-chlorobenzoate:: Mo3S4(DTP)3(p-ClC6H4COO)(Py)•EtOH and Mo3S4(DTP)3(P-ClC6H4COO)(DMF)
    Qin, YY
    Tang, YH
    Kang, Y
    Li, ZH
    Hu, RF
    Cheng, HK
    Wen, YH
    Yao, YG
    JOURNAL OF MOLECULAR STRUCTURE, 2004, 707 (1-3) : 235 - 239
  • [25] Synthesis, molecular and electronic structures of a paramagnetic trimetallic cluster containing an unusual Mo3(μ3-Se)2(μ-Se)3 core
    Petrov, Pavel A.
    Ryzhikov, Maxim R.
    Virovets, Alexander V.
    Konchenko, Sergey N.
    Gomez-Garcia, Carlos J.
    Llusar, Rosa
    POLYHEDRON, 2014, 81 : 6 - 10
  • [26] Synthesis and Crystal Structure of an Incomplete Cubane-type Mo3S4 Cluster with the N-N-O Type Tridentate Ligand: {Mo3S4[NH2CH2CH（O）CH2NH2]3}（DTP）·（H2O）2·（DMF）
    HU Rui-Feng QIN Ye-Yan KANG Yao ZHANG Jian WEN Yi-Hang LI Zhao-Ji CHEN Jiu-Tong YAO Yuan-Gen (State Key Laboratory of Structural Chemistry
    Chinese Journal of Structural Chemistry, 2005, (07) : 751 - 754
  • [27] Mechanism of [3+2] Cycloaddition of Alkynes to the [Mo3S4(acac)3(py)3][PF6] Cluster
    Angel Pino-Chamorro, Jose
    Gushchin, Artem L.
    Jesus Fernandez-Trujillo, M.
    Hernandez-Molina, Rita
    Vicent, Cristian
    Algarra, Andres G.
    Basallote, Manuel G.
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (07) : 2835 - 2844
  • [28] Synthesis and crystal structure of an incomplete cubane-typeMo3S4 cluster with the N-N-O type tridentate ligand:: {Mo3S4[NH2CH2CH(O)CH2NH2]3}(DTP)•(H2O)2•(DMF)
    Hu, RF
    Qin, YY
    Kang, Y
    Zhang, J
    Wen, YH
    Li, ZJ
    Chen, JT
    Yao, YG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (07) : 751 - 754
  • [29] Synthesis, structure, and substitution reactivity of a new bi-oxo capped molybdenum cluster: [Mo3(μ3-O)2(μ-O2CCH2Cl)6(H2O)2(OH)]
    Pineda, Kris A.
    Fettinger, James C.
    Houston, Jacqueline R.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 48 : 90 - 93
  • [30] Synthesis　and　Crystal　Structure　of　Mixed　Mo－W　Cubane－type　Cluster　Compound　［Mo2W2S4（μ－OAc）2（dtp）3（dtpH）］·CH2Cl2
    Chen Qiu-Hua
    Lu Shao-Fang
    Zhuang Yun-He
    Huang Xiao-Ying
    Huang Jian-Quan (State Key Laboratory of Structural Chemistry
    结构化学, 1995, (02) : 97 - 101
12345