Solubility of β-cyclodextrin in different mixed solvents

被引：0

作者：

Yu Yong Li Jiguang Sun Yan Liang Qianqing Peng Xiaoming Liu Yansheng Hu Yufeng Laboratory of Green Chemistry and Chemical EngineeringChina University of PetroleumBeijing China ^{[102249
]}

机构：

来源：

Petroleum Science | 2008年 / 03期

关键词：

β-cyclodextrin; ionic liquid; solubility; mixed solvent;

D O I：

暂无

中图分类号：

O636.1 [高分子多聚糖];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

<正>The solubility ofβ-cyclodextrin （β-CD） in ionic liquid/N,N-dimethyl-acetamide （IL/DMAC） mixed solvent and in LiCI/DMAC mixed solvent was investigated at 323.15 K and 353.15 K.The results showed that the solubility ofβ-CD in IL/DMAC system increased with increasing temperature,but decreased in LiCI/DMAC system.β-CD had the highest solubility in IL/DMAC system with [Cl]- or [Br]- anions.The solubility ofβ-CD in LiCl/DMAC system was lower than that in IL/DMAC system with [Cl]- or [Br]- anions but higher than that in IL/DMAC system with weak-coordinated anions （e.g [BF4]- or [PF6]-）.The effects of substituent groups （benzyl and butyl） of cation and the structure of cations onβ-cyclodextrin solubility were also investigated.

引用

页码：263 / 268

页数：6

共 3 条

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Liu Yansheng Zhang Zhongxin Zhang Guofu Liu Zhichang Hu Yufeng Shi Quan and Ji Dejun Faculty of Chemical Science and Engineering China University of Petroleum Beijing China .

Petroleum Science, 2006, (03) :73-78

[2]

Studies on catalytic spectrophotometry using β-cyclodextrin polymer–Schiff base metal complex as mimetic enzyme[J] . Bo Tang,Guo-Ying Zhang,Yang Liu,Fang Han.Analytica Chimica Acta . 2002 (1)

[3]

Solubility behavior ofβ-cyclodextrin in water/cosolvent mixtures .2 Chatjigakis A K,Donze C,Coleman A W. Analytical Chemistry . 1992

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