Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds

被引:0
作者
Ai Jun LI1
机构
关键词
N-Alkylhydroxylamines; O-alkylhydroxylamines; concerted addition mechanism; α; β-unsaturated nitro compounds; stereoselectivity;
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中图分类号
O621.25 [];
学科分类号
070303 ; 081704 ;
摘要
N-Alkylhydroxylamines have been shown to undergo a stereospecific cis addition to 1-phenyl-2 -nitropropene compounds,whereas the corresponding O-alkylhydroxylamines give no diastereoselectivity. The concerted addition mechanism was provided to explain the difference.
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页码:859 / 862
页数:4
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