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Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds
被引：0
作者：
Ai Jun LIJi Cheng CHUHong Sheng GUOXue Qin ZHOUDong Zhi LIU School of Chemical Engineering and TechnologyTianjin UniversityTianjin Medical CollegeChinese Peoples Armed Police ForceTianjin
[1
,1
,2
,1
,1
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,300072
,2
,300071
]
机构：
关键词：
N-Alkylhydroxylamines;
O-alkylhydroxylamines;
concerted addition mechanism;
α;
β-unsaturated nitro compounds;
stereoselectivity;
D O I：
暂无
中图分类号：
O621.25 [];
学科分类号：
070303 ;
081704 ;
摘要：
N-Alkylhydroxylamines have been shown to undergo a stereospecific cis addition to 1-phenyl-2 -nitropropene compounds,whereas the corresponding O-alkylhydroxylamines give no diastereoselectivity. The concerted addition mechanism was provided to explain the difference.
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页码：859 / 862
页数：4
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