牛磺酸合铜螯合物的合成及晶体结构

被引:13
作者
钟凡
蒋毅民
张淑华
机构
[1] 江西吉安市井冈山师范学院化学系
[2] 广西师范大学化学化工系
关键词
铜配合物; 牛磺酸; 晶体结构; 螯合物;
D O I
暂无
中图分类号
O641 [结构化学];
学科分类号
摘要
The new chelate complex formulated [Cu(NC2H6SO3)(phen)(CH3CO2)]·2H2O (phen is o phenanthroline) has been synthesized and the crystal structure was determined by X ray diffraction. The crystal structure of the complex belongs to triclinic system with space group and unite cell parameters: a=7.298(1)?, b=11.573(2)?, c=11.942(3)?;α=69.77(1)°, β=80.05(1)°, γ=76.39(1)°, V=915.2(3)?3, Z=2, F(000)=478. Dc=1.680g·cm-3, μ=1.354mm-1, S=1.045. In the crystal structure Cu?ion is five coordinated to form a distorted tragonal cone. CCDC: 193112.
引用
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页码:599 / 602
页数:4
相关论文
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  • [1] SturmanJ.A.J. PhysicalRev . 1993