Preparation and characterization of perfluorosulfonic resin/titania hybrid transparent films

被引:0
作者
LI JianMeiXUE MinZhaoZHANG YongMing LIU YanGang College of Chemistry and Chemical EngineeringShanghai Jiaotong UniversityShanghai China [200240 ]
机构
关键词
perfluorosulfonic resin; hybrid; titania;
D O I
暂无
中图分类号
TQ320.721 [];
学科分类号
0805 ; 080502 ;
摘要
Preparation and characterization of perfluorosulfonic resin/titania organic-inorganic hybrid films were presented. The transparent hybrid films were prepared by hydrothermal treatment at low temperature of a mixed solution of tetrabutyl titanate and perfluorosulfonic resin with the help of acetylacetone. The characterization was carried out by SEM,XRD,FT-IR,UV-Vis and TGA. The results showed that the perfluorosulfonic resin/titania hybrid transparent films were composed of titania particles dispersed in the perfluorosulfonic resin matrix very well and the titania was of anatase phase. Its diameter de-creased with increasing weight ratio of titania to perfluorosulfonic resin.
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页码:243 / 248
页数:6
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共 17 条
[1]  
Fan F R,Liu H Y,Bard J.Integrated chemical system: Photocatalysis at TiO2 incorporated into nafion and clay. The Journal of Physical Chemistry . 1985
[2]  
Rollins H W,Lin F,Johnson J,et al.Nanoscale cavities for nanopar- ticles in perfluorinated ionomer membranes. Langmuir . 2000
[3]  
Perrin F X,Nguyen V,Vernet J L.Preparation and properties of acrylic polymers/titania hybrid materials prepared by the in situ sol-gel process. Polymer International . 2002
[4]  
Legrand-Buscema C,Malibert C,Bach S.Elaboration and charac- terization of thin films of TiO2 prepared by sol-gel process. Thin Solid films . 2002
[5]  
Mauritz A.Organic-inorganic hybrid materials: Perfluorinated iono- mer as sol-gel polymerization templates for inorganic alkoxides. Materials Science and Engineering . 1998
[6]  
Park S,Clark B L,Keszler D A,et al.Low-temperature thin-film deposition and crystallization. Science . 2002
[7]  
Bertoncello P,Notargiacomo N,Nicolini C.Langmuir-Schaefer films of nafion with incorporated TiO2 nanoparticles. Langmuir . 2005
[8]  
Klug H P,Alexander L E.X-ray Diffraction Procedures. . 1956
[9]  
Kallala M A,Sanchez C,Cabane B.Structures of inorganic polymers in sol-gel processes based on titanium oxide. Physical Review E Statistical Nonlinear and Soft Matter Physics . 1993
[10]  
Petrucci G L,Fenwick D,Kakkar A K.A new catalytic hybrid mate- rial from simple acid-base hydrolytic chemistry. Journal of Molecular Catalysis A Chemical . 1999