Enantioselective Hydrolysis of α-Amino Acid Ester by Chiral Metallomicelles

被引：0
|
作者：
Jing Song YOU
Xiao Qi YU
Xiao Ling ZHANG and Ru Gang XIE(Department of Chemistry
机构：
来源：
ChineseChemicalLetters | 1998年 / 04期
关键词：
micelle; chiral metallomicelle; enantioselective hydrolysis;
D O I：
暂无
中图分类号：
O621 [有机化学一般性问题];
学科分类号：
070303 ; 081704 ;
摘要：
A series of chiral lipophilic Cu(Ⅱ) complexes were investigated as catalysts for the enantioselective hydrolysis of R(S)-p-nitrophenyl N-dodecanoyl-phenylalaninate in micelles. The highest enantioselectivity (kR/ks=7. 81) was observed in a mixed micellar system composed of 1-Cu(Ⅱ) and Brij35.
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页码：335 / 337
页数：3
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