Synthesis,Structure and Photoluminescence of a New Cadmium(Ⅱ) Complex Involving in situ Decarboxylation

被引：0

作者：

陈兰芬 ^{[1
]}

覃业燕 ^{[1
]}

李兆基 ^{[1
]}

姚元根 ^{[1
]}

机构：

[1] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences,Fuzhou, Fujian 350002, China

来源：

Chinese Journal of Structural Chemistry | 2009年 / 02期

关键词：

cadmium; pyrazine-2; 3-dicarboxylate; decarboxylation; photoluminescence;

D O I：

10.14102/j.cnki.0254-5861.2009.02.017

中图分类号：

O627.23 [锌族金属有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

A new luminescent dinuclear cluster complex [Cd2(pzc)2(AmTAZ)(H2O)4(NO3)]·NO3 (Hpzc = pyrazine-2-carboxylic acid, AmTAZ = 3-amino-4H-1,2,4-triazole) has been prepared by the assembly of CdII with pyrazine-2,3-dicarboxylic acid and 3-amino-1H-1,2,4-triazole-5-car-boxylic acid ligands under hydrothermal conditions, in which in situ decarboxylation of H2pzdc and HAmTZC ligands simultaneously occurred, and H2pzdc was transformed into Hpzc while HAmTZC into AmTAZ. The crystal structure is of triclinic, space group P1 with a = 7.096(2), b = 11.140(4), c = 14.887(5), α = 92.641(4), β = 91.348(6), γ = 96.058(6)°, V = 1168.5(7)3, C12H18Cd2N10O14, Mr = 751.16, Z = 2, Dc = 2.126 g/cm3, F(000) = 730, μ = 1.910 mm-1, R = 0.0320 and wR = 0.0998 for 4549 observed reflections (I > 2σ(I)). The dinuclear cluster of 1 is extended into a 3D supramolecular architecture through intermolecular hydrogen bonding interactions. Complex 1 exhibits strong blue photoluminescence at room temperature.

引用

页码：223 / 227

页数：5