SolvothermalSynthesisandCrystalStructureofaNovelInorganic-OrganicHybridMaterial,Fe2O（OH）(C5H4NCOO)SO4

被引：0

作者：

郭洪猷

李增和

李秀艳

张长远

王如骥

机构：

[1] DepartmentofChemistry,BeijingUniversityofChemicalTechnology,DepartmentofChemistry,BeijingUniversityofChemicalTechnology,DepartmentofChemistry,BeijingUniversityofChemicalTechnology,DepartmentofChemistry,BeijingUniversityofChemicalTechnology,DepartmentofChem

来源：

Chinese Journal of Chemistry | 2003年 / 04期

关键词：

inorganic organic hybrid material; ferric isonicotinate sulphate; solvothermal synthesis; crystal structure;

D O I：

暂无

中图分类号：

O627 [元素有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

A novel inorganic organic hybrid material, Fe 2O（OH）(C 5H 4 NCOO)SO 4 was synthesized via solvothermal route using a reaction of FeCl 3·6H 2O, KCNS, and 4 cyanopyridine in aqueous solution of H 2O 2 and ethanol at 130 ℃ for 3 d. The compound crystallized in monoclinic space group P 2 1, with cell parameters a =0 73850（15） nm, b =0 65100（13） nm, c =1 0546（2） nm, β =90 36（3）°, V =0 50700（18） nm 3 and Z =2. The structure is constructed with inorganic layered [Fe 2O（OH）SO 4] + cations linked by organic （C 5H 4NCOO） - anions. The compound is thermally stable up to approximately 240 ℃.

引用

页码：466 / 470+364 +364

页数：6