Total synthesis of cis-shisool

被引：0

作者：

WANG

机构：

来源：

ChineseJournalofChemistry | 1990年 / 01期

关键词：

Total synthesis of cis-shisool; cis;

D O I：

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摘要：

This paper describes the total sythesis of cis-shisool through intermediate 3,which wasderived from the Diels-Alder adduct 4（or 5）.The structure of the isomers produced by the Diels-Alderreaction of cyclohexadiene and crotonate has been elucidated by means of GC and NMR.Methylena-tion of 12 with Zn-CHBr-TiClor PhP=CHretains the stereochemistry of the carbon atom ad-jacent to the carbonyl group.

引用

页码：75 / 83

页数：9