Efficient and ligand free palladium catalyst for Suzuki and Heck cross-coupling reactions

被引：0
|
作者：
LUO Bin [1 ]
WANG JiaQing [1 ]
GE DanHua [1 ]
LI XinMing [1 ]
CAO XueQin [1 ]
PAN Yue [1 ]
GU HongWei [1 ]
机构：
[1] Key Laboratory of Organic Synthesis of Jiangsu Province,College of Chemistry,Chemical Engineering and Materials Science,Soochow University
来源：
Science China(Chemistry) | 2014年 / 09期
基金：
中国国家自然科学基金;
关键词：
Suzuki coupling; ligand free; Heck reaction; Pd(acac)2; biaryl;
D O I：
暂无
中图分类号：
O621.251 [];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and efficient system for Suzuki cross-coupling reactions was developed using a ligandless catalyst of Pd nanoclusters generated in situ from Pd(acac)2. The cross-coupling reactions proceeded under mild reaction conditions with a high reaction rate(5 min) to give various biaryls in high yields. The system also exhibited catalytic potential for Heck reaction between aryl bromides and styrene.
引用
收藏
页码：1310 / 1314
页数：5
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