Efficient and ligand free palladium catalyst for Suzuki and Heck cross-coupling reactions

被引：0
|
作者：
LUO Bin [1 ]
WANG JiaQing [1 ]
GE DanHua [1 ]
LI XinMing [1 ]
CAO XueQin [1 ]
PAN Yue [1 ]
GU HongWei [1 ]
机构：
[1] Key Laboratory of Organic Synthesis of Jiangsu Province,College of Chemistry,Chemical Engineering and Materials Science,Soochow University
来源：
Science China(Chemistry) | 2014年 / 09期
基金：
中国国家自然科学基金;
关键词：
Suzuki coupling; ligand free; Heck reaction; Pd(acac)2; biaryl;
D O I：
暂无
中图分类号：
O621.251 [];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and efficient system for Suzuki cross-coupling reactions was developed using a ligandless catalyst of Pd nanoclusters generated in situ from Pd(acac)2. The cross-coupling reactions proceeded under mild reaction conditions with a high reaction rate(5 min) to give various biaryls in high yields. The system also exhibited catalytic potential for Heck reaction between aryl bromides and styrene.
引用
收藏
页码：1310 / 1314
页数：5
相关论文
共 50 条
  • [21] PVC-Supported Palladium Nanoparticles: An Efficient Catalyst for Suzuki Cross-Coupling Reactions at Room Temperature
    Samarasimhareddy, Mamidi
    Prabhu, Girish
    Vishwanatha, Thimmalapura M.
    Sureshbabu, Vommina V.
    SYNTHESIS-STUTTGART, 2013, 45 (09): : 1201 - 1206
  • [22] Fluorous phase soluble palladium nanoparticles as recoverable catalysts for Suzuki cross-coupling and Heck reactions
    Moreno-Mañas, M
    Pleixats, R
    Villarroya, S
    ORGANOMETALLICS, 2001, 20 (22) : 4524 - 4528
  • [23] Palladium Nanoparticles on Assorted Nanostructured Supports: Applications for Suzuki, Heck, and Sonogashira Cross-Coupling Reactions
    Hong, Kootak
    Sajjadi, Mohaddeseh
    Suh, Jun Min
    Zhang, Kaiqiang
    Nasrollahzadeh, Mahmoud
    Jang, Ho Won
    Varma, Rajender S.
    Shokouhimehr, Mohammadreza
    ACS APPLIED NANO MATERIALS, 2020, 3 (03) : 2070 - 2103
  • [24] Polymer hydrogel confined palladium nanoparticles as recyclable catalysts for Suzuki and Heck cross-coupling reactions
    Zhan, Kan
    Lu, Ping
    Dong, Jian
    Hou, Xu
    CHINESE CHEMICAL LETTERS, 2020, 31 (06) : 1630 - 1634
  • [25] Efficient imidazolium salts for palladium-catalyzed Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions
    Mojtaba Amini
    Mojtaba Bagherzadeh
    Sadegh Rostamnia
    ChineseChemicalLetters, 2013, 24 (05) : 433 - 436
  • [26] Efficient imidazolium salts for palladium-catalyzed Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions
    Amini, Mojtaba
    Bagherzadeh, Mojtaba
    Rostamnia, Sadegh
    CHINESE CHEMICAL LETTERS, 2013, 24 (05) : 433 - 436
  • [27] Dendritic structured palladium complexes: magnetically retrievable, highly efficient heterogeneous nanocatalyst for Suzuki and Heck cross-coupling reactions
    Sheikh, Safoora
    Nasseri, Mohammad Ali
    Chahkandi, Mohammad
    Reiser, Oliver
    Allahresani, Ali
    RSC ADVANCES, 2022, 12 (15) : 8833 - 8840
  • [28] Polymer hydrogel confined palladium nanoparticles as recyclable catalysts for Suzuki and Heck cross-coupling reactions
    Kan Zhan
    Ping Lu
    Jian Dong
    Xu Hou
    Chinese Chemical Letters, 2020, 31 (06) : 1630 - 1634
  • [29] Ligand effects in palladium-catalyzed Suzuki and Heck coupling reactions
    Hanhan, M. Emre
    APPLIED ORGANOMETALLIC CHEMISTRY, 2008, 22 (05) : 270 - 275
  • [30] Impregnated palladium on magnetite, a new catalyst for the ligand-free cross-coupling Suzuki-Miyaura reaction
    Cano, Rafael
    Ramon, Diego J.
    Yus, Miguel
    TETRAHEDRON, 2011, 67 (30) : 5432 - 5436
12345