Efficient and ligand free palladium catalyst for Suzuki and Heck cross-coupling reactions

被引：0

作者：

LUO Bin ^{[1
]}

WANG JiaQing ^{[1
]}

GE DanHua ^{[1
]}

LI XinMing ^{[1
]}

CAO XueQin ^{[1
]}

PAN Yue ^{[1
]}

GU HongWei ^{[1
]}

机构：

[1] Key Laboratory of Organic Synthesis of Jiangsu Province,College of Chemistry,Chemical Engineering and Materials Science,Soochow University

来源：

Science China(Chemistry) | 2014年 / 09期

基金：

中国国家自然科学基金;

关键词：

Suzuki coupling; ligand free; Heck reaction; Pd(acac)2; biaryl;

D O I：

暂无

中图分类号：

O621.251 [];

学科分类号：

摘要：

A simple and efficient system for Suzuki cross-coupling reactions was developed using a ligandless catalyst of Pd nanoclusters generated in situ from Pd(acac)2. The cross-coupling reactions proceeded under mild reaction conditions with a high reaction rate(5 min) to give various biaryls in high yields. The system also exhibited catalytic potential for Heck reaction between aryl bromides and styrene.

引用

页码：1310 / 1314

页数：5

共 50 条

[1] Efficient and ligand free palladium catalyst for Suzuki and Heck cross-coupling reactions
Bin Luo
JiaQing Wang
DanHua Ge
XinMing Li
XueQin Cao
Yue Pan
HongWei Gu
Science China Chemistry, 2014, 57 : 1310 - 1314
[2] Efficient and ligand free palladium catalyst for Suzuki and Heck cross-coupling reactions
Luo Bin
Wang JiaQing
Ge DanHua
Li XinMing
Cao XueQin
Pan Yue
Gu HongWei
SCIENCE CHINA-CHEMISTRY, 2014, 57 (09) : 1310 - 1314
[3] Efficient and ligand free palladium catalyst for Suzuki and Heck cross-coupling reactions
LUO Bin
WANG JiaQing
GE DanHua
LI XinMing
CAO XueQin
PAN Yue
GU HongWei
Science China(Chemistry), 2014, 57 (09) : 1310 - 1314
[4] Palladium ethylthioglycolate modified silica - a new heterogeneous catalyst for Suzuki and Heck cross-coupling reactions
Al-Hashimi, Mohammed
Sullivan, Alice C.
Wilson, John R. H.
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 273 (1-2) : 298 - 302
[5] Silica-supported terpyridine palladium(II) complex as an efficient and reusable catalyst for Heck and Suzuki cross-coupling reactions
Amini, Mostafa M.
Feiz, Afsaneh
Dabiri, Minoo
Bazgir, Ayoob
APPLIED ORGANOMETALLIC CHEMISTRY, 2014, 28 (02) : 86 - 90
[6] Novel polymer supported iminopyridylphosphine palladium (II) complexes: An efficient catalyst for Suzuki-Miyaura and Heck cross-coupling reactions
Liu, Xiang
Zhao, Xiaohua
Lu, Ming
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 768 : 23 - 27
[7] The Current Status of Heterogeneous Palladium Catalysed Heck and Suzuki Cross-Coupling Reactions
Mpungose, Philani P.
Vundla, Zanele P.
Maguire, Glenn E. M.
Friedrich, Holger B.
MOLECULES, 2018, 23 (07):
[8] Palladium Nanoparticles as Efficient Catalysts for Suzuki Cross-Coupling Reactions
Perez-Lorenzo, Moises
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (02): : 167 - 174
[9] A convenient palladium/ligand catalyst for Suzuki cross-coupling reactions of arylboronic acids and aryl chlorides
Bei, XH
Crevier, T
Guram, AS
Jandeleit, B
Powers, TS
Turner, HW
Uno, T
Weinberg, WH
TETRAHEDRON LETTERS, 1999, 40 (20) : 3855 - 3858
[10] Finely dispersed palladium on silk-fibroin as an efficient and ligand-free catalyst for Heck cross-coupling reaction
Mirzaei, Hakimeh
Eshghi, Hossein
Seyedi, Seyed Mohammad
APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (11)

← 1 2 3 4 5 →