A New Chiral β-Sulfiny Dienophile for Asymmetric Diels-Alder Reaction

被引：0

作者：

YANG TengKuei

HUNG ShunMing

CHEN ChinZon

JIANG YaoZhong

MI AiQiao Department of Chemistry National ChungHsing University Taichung Taiwan Chengdu Institute of Organic Chemistry Academia Sinica Chengdu ^{[40227
,610015
]}

机构：

来源：

有机化学 | 1993年 / 02期

关键词：

asymmetric Diels-Alder Reaction; Chiral auxiliary; (+)-camphor;

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学科分类号：

摘要：

<正> Reaction of a chiral cis-β-sulfinylacrylate, prepared from (1R,2S,3R)-3-mercapto-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol, and cyclopentadiene produced Diels-Alder cycloadductswith extremely high diastereoselectivity.

引用

页码：183 / 185

页数：3