CRYSTAL AND MOLECULAR STRUCTURE OF 4-CHLORO-5- ETHYL-5-METHYL-3-PHENYL-1, 3, 4-DIAZAPHOSPHOLIDIN-2-THIONE-4-SULFIDE

被引：0
|
作者：
Feng Ke-Sheng Chen Ru-YuInstitute of Elemento-Organii Chemistry
机构：
来源：
结构化学 | 1993年 / 05期
关键词：
Heterocycle Compound Crystal Structure;
D O I：
10.14102/j.cnki.0254-5861.1993.05.011
中图分类号：
学科分类号：
摘要：
Crystal of the title compound Mr=304. 80 belongs to the triclinic, space group P1, with a = 7. 282)2), b=9. 064(2), c=11. 737(5) A , α=75. 79 (3), β=78. 70(3), γ=88. 49(2)°, V-736. 21 A3, Z=2, Dx = l. 375 g/cm3. The final refinement is converged with R=0. 062 and Rw= 0. 069.The five-membered heterocycle is in envelope conformation. The P - N bond length (1. 68(1)) indicates that the dπ-Pπ bond between P and N of the title compound is stronger than that of the corresponding 4-phenyl compound.
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页码：380 / 382
页数：3
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