Synthesis and Crystal Structure of Palladium(Ⅱ) Complex with 2,2’-Bipyridine-3,3’-dicarboxylic Acid

被引：0

作者：

刘瑕 ^{[1
]}

高恩君 ^{[2
]}

程卯生 ^{[3
]}

孙亚光 ^{[1
]}

机构：

[1] Laboratory of Coordination Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142, China

[2] Laboratory of Coordination Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142, China College of Pharmaceutical Engineering, Shenyang Pharmaceutical University, Shenyang 110015, China

[3] College of Pharmaceutical Engineering, Shenyang Pharmaceutical University, Shenyang 110015, China

来源：

Chinese Journal of Structural Chemistry | 2006年 / 04期

基金：

美国国家科学基金会;

关键词：

palladium complex; 2; 2’-bipyridine-3; 3’-dicarboxylic acid; crystal structure;

D O I：

10.14102/j.cnki.0254-5861.2006.04.017

中图分类号：

O621.25 [];

学科分类号：

070303 ; 081704 ;

摘要：

The title complex Pd(H2BDA)Cl2’2DMSO (C16H14Cl2N2O6PdS2, H2BDA = 2,2’- bipyridine-3,3’-dicarboxylic acid) has been synthesized and characterized by IR spectra, elemental analysis and 1H NMR spectra. Its structure was determined by single-crystal X-ray diffraction analysis. The complex crystallizes in the monoclinic system, space group P21/c with a = 1.3604(6), b = 1.2606(6), c = 1.3521(6) nm, β = 103.677(7)o, V = 2.2530(17) nm3, Mr = 571.75, Z = 4, Dc = 1.686 g/cm3, μ = 1.280 mm–1, F(000) = 1136, R = 0.0405 and wR = 0.0908. The complex presents a planar quadrangle arrangement and is assembled via hydrogen bonds.

引用

页码：477 / 480

页数：4