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高度可溶聚苝酰亚胺材料的合成及性能研究
被引：6
作者：
黄卫
颜德岳
路庆华
机构：
[1] 上海交通大学化学化工学院
[2] 上海交通大学化学化工学院 上海
[3] 上海
来源：
关键词：
苝;
聚酰亚胺;
可溶性;
荧光;
D O I：
暂无
中图分类号：
TQ323 [缩聚类树脂及塑料];
学科分类号：
0805 ;
080502 ;
摘要：
A series of high molecular weight copolyimides containing various amounts of perylene units in the main-chain were synthesized. The products were characterized by FTIR, NMR, UV-Vis, fluorescence spectroscopy, GPC, DSC and TGA measurements. They are highly soluble in conventional solvents such as chloroform, THF, cyclohexanone etc. and form optically transparent films by solution casting or spin-coating. The copolyimide containing 0.5%(molar fraction) perylene units exhibits the highest solid-state fluorescence. The polyimides are thermally stable up to 400 ℃ and exhibit glass transition temperatures in the range of 340～360 ℃. The number-average molecule weight ranges from 1.72×10 4 to 1.25×10 5 and the molecule weight distribution mediated between 1.9 to 2.4.
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页码：2005 / 2007
页数：3
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